Thermal- and microwave-assisted hydrogenation of electron-deficient alkenes using a polymer-supported hydrogen donor

2001 ◽  
Vol 42 (34) ◽  
pp. 5963-5965 ◽  
Author(s):  
Bimbisar Desai ◽  
Timothy N Danks
2005 ◽  
Vol 83 (5) ◽  
pp. 517-520 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R Srinivasa ◽  
D Channe Gowda

Palladium-catalyzed room temperature transfer hydrogenation of azo compounds using recyclable polymer-supported formate as the hydrogen donor produces corresponding amine(s) in excellent yields (88%–98%). This method was found to be highly facile with selectivity over a number of other functional groups such as halogen, alkene, nitrile, carbonyl, amide, methoxy, and hydroxyl.Key words: azo compounds, catalytic transfer hydrogenation, polymer-supported formate, 10% Pd-C, amines.


2017 ◽  
Vol 58 (27) ◽  
pp. 2670-2674 ◽  
Author(s):  
Sung-Jun Park ◽  
Hong-Jun Cho ◽  
Sang-Myung Lee ◽  
Yoon-Sik Lee

RSC Advances ◽  
2015 ◽  
Vol 5 (59) ◽  
pp. 47275-47283 ◽  
Author(s):  
Abu Taher ◽  
Debkumar Nandi ◽  
Rafique Ul Islam ◽  
Meenakshi Choudhary ◽  
Kaushik Mallick

Microwave assisted solvent less approach for azide–alkyne cycloaddition.


2005 ◽  
Vol 58 (2) ◽  
pp. 149 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R. Srinivasa ◽  
D. Channe Gowda

Aromatic nitro compounds were chemoselectively reduced to the corresponding amines using recyclable polymer-supported formate as a hydrogen donor in the presence of low-cost magnesium powder at room temperature. Use of the immobilized hydrogen donor affords the product amine in excellent yield (90–97%) without the need for any chromatographic purification steps. This method was found to be highly facile with selectivity over several other functional groups, such as halogen, alkene, nitrile, carbonyl, ester, amide, methoxy, phenol, and hydroxyl groups.


ChemInform ◽  
2015 ◽  
Vol 46 (42) ◽  
pp. no-no
Author(s):  
Abu Taher ◽  
Debkumar Nandi ◽  
Rafique Ul Islam ◽  
Meenakshi Choudhary ◽  
Kaushik Mallick

2003 ◽  
Vol 10 (22) ◽  
pp. 2403-2423 ◽  
Author(s):  
K. Swamy ◽  
Wen-Ben Yeh ◽  
Mei-Jung Lin ◽  
Chung-Ming Sun

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