Synthesis and reactions of dimolybdenum(II,II), diruthenium(II,III) and dicopper(II,II) complexes containing unsaturated aliphatic carboxylate bridging ligands: X-ray crystal structure of [Ru2(μ-O2C(CH3)Cz.dbnd&2;CH2)4Cl]

Polyhedron ◽  
1991 ◽  
Vol 10 (19) ◽  
pp. 2273-2281 ◽  
Author(s):  
Malachy McCann ◽  
Andrew Carvill ◽  
Pauline Guinan ◽  
Paula Higgins ◽  
James Campbell ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Bridging Ligands ◽  
X Ray

Binuclear Iron and Ruthenium Complexes with Bis(diazene) or Bis(diazenido) Bridging Ligands:  Synthesis, Characterization, X-ray Crystal Structure, and Electrochemical Studies

1996 ◽  
Vol 35 (21) ◽  
pp. 6245-6253 ◽  
Author(s):  
Gabriele Albertin ◽  
Stefano Antoniutti ◽  
Alessia Bacchi ◽  
Emilio Bordignon ◽  
Giancarlo Pelizzi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Ruthenium Complexes ◽  
Electrochemical Studies ◽  
Bridging Ligands ◽  
X Ray ◽  
Binuclear Iron

Binuclear copper(I) complexes containing bis(diphenylphosphino)methane bridging ligands. X-ray crystal structure of [Cu2(dppm)2(Py)2(NO3)](NO3) · CH3OH

Polyhedron ◽  
1997 ◽  
Vol 16 (23) ◽  
pp. 4033-4038 ◽  
Author(s):  
Yang Ruina ◽  
Lin Kunhua ◽  
Hou Yimin ◽  
Wang Dongmei ◽  
Jin Douman
Keyword(s):  
Crystal Structure ◽  
Binuclear Copper ◽  
Bridging Ligands ◽  
X Ray

Crystal structure of the three-dimensional magnetic network of type Mek[Fe(CN)6]l·mH2O, where Me=Cu, Ni, Co

1995 ◽  
Vol 10 (4) ◽  
pp. 300-305 ◽  
Author(s):  
A. Ratuszna ◽  
S. Juszczyka ◽  
G. Małecki
Keyword(s):  
Crystal Structure ◽  
Powder Diffraction ◽  
Diffraction Data ◽  
Three Dimensional ◽  
Powder Diffraction Data ◽  
Bridging Ligands ◽  
X Ray ◽  
C And N ◽  
Fe Sites ◽  
Magnetic Network

The crystal structures of Mek[Fe(CN)6];l·mH2O where Me = Cu, Ni and Co, have been refined from X-ray (CuKa) powder diffraction data by means of Rietveld analyses in space group . The Fe and Me ions are octahedrally coordinated by C and N atoms respectively, forming three-dimensional bimetallic networks with the CN-groups as bridging ligands. The Me(l) sites (k = 2, l=1) and the Fe sites (k = 3, l = 2) are partially occupied. Water oxygens were placed in alternative, empty metal sites.

Crystal structure of cyanometallates Me3[Co(CN)6]2 and KMe[Fe(CN)6] with Me=Mn2+, Ni2+, Cu2+

1999 ◽  
Vol 14 (1) ◽  
pp. 25-30 ◽  
Author(s):  
Grzegorz Małecki ◽  
Alicja Ratuszna
Keyword(s):  
Crystal Structure ◽  
Rietveld Method ◽  
Three Dimensional ◽  
Lattice Parameters ◽  
Powder Diffraction Data ◽  
Bridging Ligands ◽  
Cubic Symmetry ◽  
X Ray ◽  
C And N ◽  
Starting Model

The crystal structure of four cyanometallates has been determined from X-ray powder diffraction data using the Rietveld method. The variously hydrated compounds Cu3[Co(CN)6]2, Mn3[Co(CN)6]2 and KNi[Fe(CN)6] crystallize at cubic symmetry (Fm3m) with lattice parameters 10.032(2), 10.413(3) and 10.234(5) Å, respectively. The crystal of KMn[Fe(CN)6]·2H2O shows a monoclinic structure (P21/c) with the lattice parameters a=10.108(2) Å, b=10.104(3) Å, c=10.114(3) Å, β=92°, 93°. The starting model was based on an isomorphic Mn3[Co(CN)6]2 single crystal structure, where Co and Mn ions are octahedrally coordinated by C and N atoms, respectively, forming three-dimensional bimetallic networks with the C≡N groups as bridging ligands.

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