Electrostatic model for substituent and solvent effects on organic acids

1997 ◽  
Vol 136 (1-2) ◽  
pp. 31-36 ◽  
Author(s):  
Xin-Gen Hu ◽  
Han-Xing Zong ◽  
Rui-Sen Lin
Keyword(s):  
Organic Acids ◽  
Solvent Effects ◽  
Electrostatic Model

Substituent and solvent effects on organic acids: an electrostatic theory

1976 ◽  
Vol 54 (8) ◽  
pp. 1296-1299 ◽  
Author(s):  
Takeki Matsui ◽  
Loren G. Hepler
Keyword(s):  
Proton Transfer ◽  
Organic Acids ◽  
Gas Phase ◽  
Solvent Effects ◽  
Transfer Reactions ◽  
Electrostatic Model ◽  
Environmental Models ◽  
Gas Phase Acidity ◽  
Proton Transfer Reactions ◽  
Electrostatic Theory

We have used an electrostatic model as basis for derived equations to represent the effects of substituents and solvents on the thermodynamics of proton transfer reactions. Equations derived in this manner are related to those based on earlier 'internal-environmental' models and are also discussed in relation to recent gas phase acidity work.

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