scholarly journals Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal–Organic Framework MAF-6

2020 ◽  
Vol 32 (5) ◽  
pp. 1784-1793 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
João Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Thin Films ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Powder Synthesis ◽  
Large Pore ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Templated Solvent-Free Powder Synthesis and MOF-CVD Films of the Ultramicroporous Metal–Organic Framework α-Magnesium Formate

2020 ◽  
Vol 32 (24) ◽  
pp. 10469-10475
Author(s):  
Dmitry E. Kravchenko ◽  
Alexander John Cruz ◽  
Sabina Rodríguez-Hermida ◽  
Nathalie Wauteraerts ◽  
Tom Hauffman ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Solvent Free ◽  
Powder Synthesis ◽  
Metal Organic ◽  
Organic Framework

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

scholarly journals Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

2019 ◽  
Vol 58 (51) ◽  
pp. 18471-18475
Author(s):  
João Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo Oliveira‐Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

In Situ Growth of Metal–Organic Framework Thin Films with Gas Sensing and Molecule Storage Properties

Langmuir ◽  
2013 ◽  
Vol 29 (27) ◽  
pp. 8657-8664 ◽  
Author(s):  
Wei-Jin Li ◽  
Shui-Ying Gao ◽  
Tian-Fu Liu ◽  
Li-Wei Han ◽  
Zu-Jin Lin ◽  
...  
Keyword(s):  
Thin Films ◽  
Gas Sensing ◽  
Metal Organic Framework ◽  
In Situ Growth ◽  
Metal Organic ◽  
Storage Properties ◽  
Organic Framework

Solvent-free route for metal-organic framework membranes growth aiming for efficient gas separation

AIChE Journal ◽  
2018 ◽  
Vol 65 (2) ◽  
pp. 712-722 ◽  
Author(s):  
Jiamin Hou ◽  
Xilu Hong ◽  
Sheng Zhou ◽  
Yanying Wei ◽  
Haihui Wang
Keyword(s):  
Gas Separation ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Organic Framework

scholarly journals General incorporation of diverse components inside metal-organic framework thin films at room temperature

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Yiyin Mao ◽  
Junwei Li ◽  
Wei Cao ◽  
Yulong Ying ◽  
Pan Hu ◽  
...  
Keyword(s):  
Thin Films ◽  
Room Temperature ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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