Biphasic Catalytic Hydrogen Peroxide Oxidation of Alcohols in Flow: Scale-up and Extraction

2016 ◽  
Vol 20 (9) ◽  
pp. 1677-1685 ◽  
Author(s):  
Maryam Peer ◽  
Nopphon Weeranoppanant ◽  
Andrea Adamo ◽  
Yanjie Zhang ◽  
Klavs F. Jensen
Keyword(s):  
Hydrogen Peroxide ◽  
Scale Up ◽  
Peroxide Oxidation ◽  
Oxidation Of Alcohols ◽  
Hydrogen Peroxide Oxidation ◽  
Catalytic Hydrogen

Crystal and solution structure of (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile

1989 ◽  
Vol 54 (12) ◽  
pp. 3253-3259
Author(s):  
Jaroslav Podlaha ◽  
Miloš Buděšínský ◽  
Jana Podlahová ◽  
Jindřich Hašek
Keyword(s):  
Hydrogen Peroxide ◽  
Solution Structure ◽  
Peroxide Oxidation ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Study ◽  
Hydrogen Peroxide Oxidation ◽  
Unusual Product ◽  
C Nmr

The unusual product of the reaction of 2-chloroacrylonitrile with ethane thiol and following hydrogen peroxide oxidation was found to be (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile by means of X-ray crystallography. 1H and 13C NMR study of this compound has proven the same conformation of the molecule in solution.

Sign in / Sign up

Export Citation Format

Share Document