Boosting Interfacial Electron Transfer between Pd and ZnTi-LDH via Defect Induction for Enhanced Metal–Support Interaction in CO Direct Esterification Reaction

2021 ◽  
Author(s):  
Kai-Qiang Jing ◽  
Yu-Qing Fu ◽  
Zhe-Ning Chen ◽  
Teng Zhang ◽  
Jing Sun ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Esterification Reaction ◽  
Interfacial Electron Transfer ◽  
Direct Esterification ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support

Electron transfer dependent catalysis of Pt on N-doped carbon nanotubes: Effects of synthesis method on metal-support interaction

2017 ◽  
Vol 348 ◽  
pp. 100-109 ◽  
Author(s):  
Xiaomei Ning ◽  
Yuhang Li ◽  
Baoqiang Dong ◽  
Hongjuan Wang ◽  
Hao Yu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electron Transfer ◽  
Synthesis Method ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support

Influence of TiO2electronic structure and strong metal–support interaction on plasmonic Au photocatalytic oxidations

2016 ◽  
Vol 6 (9) ◽  
pp. 3220-3229 ◽  
Author(s):  
Alberto Naldoni ◽  
Francesca Riboni ◽  
Marcello Marelli ◽  
Filippo Bossola ◽  
Giacomo Ulisse ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hot Electron ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Hot Electron Transfer ◽  
Strong Metal Support Interaction

Photocatalytic oxidations promoted by hot electron transfer and PRET strongly depend on Au loading and SMSI.

Isomorphic titanium-substituted mesoporous SBA-16 as support for cobalt Fischer–Tropsch synthesis catalysts: Balance between dispersion and reduction

2021 ◽  
Author(s):  
Liang Wei ◽  
Jian Chen ◽  
Shuai Lyu ◽  
Chengchao Liu ◽  
Yanxi Zhao ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Support Interaction ◽  
Delicate Balance ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Synthesis Catalysts

The delicate balance between dispersion and reduction of the Co-based Fischer–Tropsch synthesis catalyst is the golden key to enhancing catalytic performance, which highly depends on an optimized metal–support interaction. In...

scholarly journals Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yi Shi ◽  
Zhi-Rui Ma ◽  
Yi-Ying Xiao ◽  
Yun-Chao Yin ◽  
Wen-Mao Huang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Structure Activity Relationship ◽  
Atomic Level ◽  
Single Atom ◽  
Activity Relationship ◽  
Support Interaction ◽  
Structure Activity ◽  
Metal Support Interaction ◽  
Metal Support

AbstractTuning metal–support interaction has been considered as an effective approach to modulate the electronic structure and catalytic activity of supported metal catalysts. At the atomic level, the understanding of the structure–activity relationship still remains obscure in heterogeneous catalysis, such as the conversion of water (alkaline) or hydronium ions (acid) to hydrogen (hydrogen evolution reaction, HER). Here, we reveal that the fine control over the oxidation states of single-atom Pt catalysts through electronic metal–support interaction significantly modulates the catalytic activities in either acidic or alkaline HER. Combined with detailed spectroscopic and electrochemical characterizations, the structure–activity relationship is established by correlating the acidic/alkaline HER activity with the average oxidation state of single-atom Pt and the Pt–H/Pt–OH interaction. This study sheds light on the atomic-level mechanistic understanding of acidic and alkaline HER, and further provides guidelines for the rational design of high-performance single-atom catalysts.

Zn2+ stabilized Pd clusters with enhanced covalent metal–support interaction via the formation of Pd–Zn bonds to promote catalytic thermal stability

Nanoscale ◽  
2020 ◽  
Vol 12 (27) ◽  
pp. 14825-14830
Author(s):  
Kai-Qiang Jing ◽  
Yu-Qing Fu ◽  
Zhi-Qiao Wang ◽  
Zhe-Ning Chen ◽  
Hong-Zi Tan ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Adsorption Energy ◽  
Catalytic Performance ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Pd Clusters

Zn2+-Modified MgAl-LDH with ultra-low Pd cluster loading was synthesized. The higher adsorption energy and strong covalent metal–support interaction via forming Pd–Zn bonds over Pd/ZnMgAl-LDH account for the robust catalytic performance.

Effects of rare earth metal doping on Au/ReZrO2 catalysts for efficient hydrogen generation from formic acid

2021 ◽  
Vol 45 (12) ◽  
pp. 5704-5711
Author(s):  
Luming Wu ◽  
Yu Hao ◽  
Shaohua Chen ◽  
Rui Chen ◽  
Pingchuan Sun ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Rare Earth ◽  
Rare Earth Metal ◽  
Oxygen Vacancies ◽  
Hydrogen Generation ◽  
Earth Metal ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Metal Doped

Rare earth metal doped ZrO2 can promote the formation of oxygen vacancies in zirconia, which enhances the metal–support interaction, finally promoting catalytic activity of FA dehydrogenation.

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