Preparations, far-infrared spectra, and Raman spectra of pentahaloindium(III) and -thallium(III) complexes

A number of different methods for preparing anionic Group 1B metal thiolate complexes have been investigated. The compounds [Me4N] [CU2(SMe)3] and [Et4N] [Ag5(SBut)6] are reported for the first time, and new methods for preparing the previously known compounds [Et4N] [Cu5(SBut)6], [Me4N]2 [CU5(SPh)7] and [Et4N]2 [Cu5(SPh)7] are described. The far-infrared spectra of the above compounds, and of CuSMe, CuSBut, AgSBut, [Me4N]2 [CU4(SPh)6] and [Me4N]2 [Ag5(SPh)7] have been obtained, and metal-sulfur stretching bands are assigned in the 150-350 cm-1 region. The low-frequency Raman spectra have also been obtained for some of these compounds. Possible structures for the new compounds are considered in the light of the low-frequency vibrational spectra.

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Far-infrared and Raman Spectra of Crystalline ICN

Canadian Journal of Chemistry ◽

10.1139/v71-403 ◽

1971 ◽

Vol 49 (14) ◽

pp. 2459-2462 ◽

Cited By ~ 5

Author(s):

R. Savoie ◽

M. Pézolet

Keyword(s):

Raman Spectra ◽

Infrared Spectra ◽

High Frequency ◽

Far Infrared ◽

Infrared And Raman Spectra ◽

Infrared Band ◽

Longitudinal Modes ◽

Intensity Measurements ◽

Cyanogen Iodide ◽

Far Infrared Spectra

The Raman and far-infrared spectra of crystalline cyanogen iodide have been recorded. High-frequency shoulders alongside the Raman bands confirm the piezoelectric nature of this solid and allow an estimate to be made of the frequencies of the longitudinal modes associated to the fundamental vibrations. Dipole derivatives calculated from these frequencies agree qualitatively with those obtained from infrared band intensity measurements.

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Raman and far infrared spectra of s-trinitrobenzene and s-trinitrobenzene-d3

Canadian Journal of Chemistry ◽

10.1139/v69-417 ◽

1969 ◽

Vol 47 (14) ◽

pp. 2515-2519 ◽

Cited By ~ 9

Author(s):

H. F. Shurvell ◽

A. R. Norris ◽

D. E. Irish

Keyword(s):

Infrared Spectrum ◽

Raman Spectra ◽

Infrared Spectra ◽

Solid Phase ◽

Far Infrared ◽

Far Infrared Spectra

Raman spectra have been recorded of s-trinitrobenzene and s-trinitrobenzene-d3 both in solution and in the solid phase. Eighteen of the 22 Raman active fundamentals in D3h have been observed for both molecules.Two fundamentals have been observed in the far infrared spectrum of each molecule.

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Far-Infrared and Raman Spectra of Ammonium Fluoride and Ammonium Fluoride—d4

Applied Spectroscopy ◽

10.1366/000370270774372227 ◽

1970 ◽

Vol 24 (1) ◽

pp. 16-20 ◽

Cited By ~ 12

Author(s):

J. R. Durig ◽

D. J. Antion

Keyword(s):

Thin Films ◽

Raman Spectra ◽

Infrared Spectra ◽

Low Frequency ◽

Far Infrared ◽

Ammonium Fluoride ◽

Isotopic Shift ◽

Lattice Vibrations ◽

Infrared And Raman Spectra ◽

Far Infrared Spectra

The far-infrared spectra of thin films of NH4F and ND4F and the Raman spectra of polycrystalline samples of both compounds have been recorded at −170°C. Two low-frequency lattice vibrations were observed in each spectrum and these have been assigned as optical translations on the basis of their isotopic shift factors. Librational modes were not observed in any of the spectra.

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Raman spectra of gaseous and solid methyl-d3-vinyl ether, a re-investigation of the far infrared spectra, and the conformational stability in the gas phase

Spectrochimica Acta Part A Molecular Spectroscopy ◽

10.1016/0584-8539(86)80170-2 ◽

1986 ◽

Vol 42 (2-3) ◽

pp. 113-122 ◽

Cited By ~ 18

Author(s):

J.F. Sullivan ◽

T.J. Dickson ◽

J.R. Durig

Keyword(s):

Gas Phase ◽

Vinyl Ether ◽

Raman Spectra ◽

Infrared Spectra ◽

Conformational Stability ◽

Far Infrared ◽

Far Infrared Spectra

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RAMAN AND INFRARED STUDY OF YBa2 Cu3 O7

International Journal of Modern Physics B ◽

10.1142/s0217979287001559 ◽

1987 ◽

Vol 01 (03n04) ◽

pp. 1057-1061

Author(s):

D. Mihailović ◽

M. Čopič ◽

M. Zgonik ◽

A. Novak

Keyword(s):

Raman Spectra ◽

Infrared Spectra ◽

Far Infrared ◽

Infrared Transmission ◽

Infrared Study ◽

Transmission Measurements ◽

Far Infrared Spectra

We have measured Raman and far-infrared spectra of YBa2 Cu3 O7 as a function of temperature. No significant changes are observed in the Raman spectra as with temperature. Far-infrared transmission measurements show a band at 100 cm −1 broadening at Tc .

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