Optically active allylsilanes. 2. High stereoselectivity in asymmetric reaction with aldehydes producing homoallylic alcohols

1982 ◽  
Vol 104 (18) ◽  
pp. 4963-4965 ◽  
Author(s):  
Tamio Hayashi ◽  
Mitsuo Konishi ◽  
Makoto Kumada
2020 ◽  
Vol 18 (3) ◽  
pp. 479-487 ◽  
Author(s):  
Seda Karahan ◽  
Cihangir Tanyeli

Bifunctional squaramide catalyzed asymmetric Mannich reaction of alpha-azido ketones and isatin derived ketiminines were established for the first time with high stereoselectivity. Adducts are valuable synthons for optically active heterocycles.


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