Exploring the Role of the Central Carbide of the Nitrogenase Active-Site FeMo-cofactor through Targeted 13C Labeling and ENDOR Spectroscopy

Author(s):  
Ana Pérez-González ◽  
Zhi-Yong Yang ◽  
Dmitriy A. Lukoyanov ◽  
Dennis R. Dean ◽  
Lance C. Seefeldt ◽  
...  
2005 ◽  
Vol 127 (17) ◽  
pp. 6231-6241 ◽  
Author(s):  
Robert Y. Igarashi ◽  
Mikhail Laryukhin ◽  
Patricia C. Dos Santos ◽  
Hong-In Lee ◽  
Dennis R. Dean ◽  
...  

Science ◽  
2021 ◽  
Vol 371 (6530) ◽  
pp. eabe5481 ◽  
Author(s):  
John W. Peters ◽  
Oliver Einsle ◽  
Dennis R. Dean ◽  
Serena DeBeer ◽  
Brian M. Hoffman ◽  
...  

Kang et al. (Reports, 19 June 2020, p. 1381) report a structure of the nitrogenase MoFe protein that is interpreted to indicate binding of N2 or an N2-derived species to the active-site FeMo cofactor. Independent refinement of the structure and consideration of biochemical evidence do not support this claim.


2000 ◽  
Vol 275 (46) ◽  
pp. 35792-35798 ◽  
Author(s):  
Isabelle Schepens ◽  
Eric Ruelland ◽  
Myroslawa Miginiac-Maslow ◽  
Pierre Le Maréchal ◽  
Paulette Decottignies

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