Excited State Two Photon Absorption of a Charge Transfer Radical Dimer in the Near Infrared

2005 ◽  
Vol 109 (21) ◽  
pp. 4643-4645 ◽  
Author(s):  
Nicola Schiccheri ◽  
Moreno Meneghetti
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
A Charge

Vibronic induced one- and two-photon absorption in a charge-transfer stilbene derivate

2007 ◽  
Vol 126 (24) ◽  
pp. 244509 ◽  
Author(s):  
Na Lin ◽  
Xian Zhao ◽  
Antonio Rizzo ◽  
Yi Luo
Keyword(s):  
Charge Transfer ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
A Charge

scholarly journals Near infrared two-photon-excited and -emissive dyes based on a strapped excited-state intramolecular proton-transfer (ESIPT) scaffold

2018 ◽  
Vol 9 (10) ◽  
pp. 2666-2673 ◽  
Author(s):  
Naoya Suzuki ◽  
Kayo Suda ◽  
Daisuke Yokogawa ◽  
Hirotaka Kitoh-Nishioka ◽  
Stephan Irle ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Intramolecular Proton Transfer ◽  
Infrared Emission ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Near Infrared Emission

Strapped acceptor–π–donor–π–acceptor type fluorophores exhibit intense near infrared emission, together with near infrared two-photon absorption.

Two-photon absorption spectra of a near-infrared 2-azaazulene polymethine dye: solvation and ground-state symmetry breaking

2013 ◽  
Vol 15 (20) ◽  
pp. 7666 ◽  
Author(s):  
Honghua Hu ◽  
Olga V. Przhonska ◽  
Francesca Terenziani ◽  
Anna Painelli ◽  
Dmitry Fishman ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Polymethine Dye

Novel A–(π–D–π–A)1–3 branched fluorophores displaying high two-photon absorption

RSC Advances ◽  
2016 ◽  
Vol 6 (52) ◽  
pp. 46853-46863 ◽  
Author(s):  
Zhi-Bin Cai ◽  
Hai-Min Shen ◽  
Mao Zhou ◽  
Sheng-Li Li ◽  
Yu-Peng Tian
Keyword(s):  
Charge Transfer ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
End Groups

Novel A–(π–D–π–A)3 compounds bearing pyridine end groups are apparently effective in achieving large two-photon responses owing to strong charge transfer.

scholarly journals Tuning of Hyperpolarizability, One- and Two-Photon Absorption of D-A and D-A-A Type Intramolecular Charge Transfer Based Sensors

2019 ◽  
Author(s):  
Pralok K. Samanta ◽  
Md Mehboob Alam ◽  
Ramprasad Misra ◽  
Swapan K. Pati
Keyword(s):  
Charge Transfer ◽  
Gas Phase ◽  
Density Functional ◽  
Intramolecular Charge Transfer ◽  
Photon Absorption ◽  
First Hyperpolarizability ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Nlo Response ◽  
Donor Acceptor

Solvents play an important role in shaping the intramolecular charge transfer (ICT) properties of π-conjugated molecules, which in turn can affect their one-photon absorption (OPA) and two-photon absorption (TPA) as well as the static (hyper)polarizabilities. Here, we study the effect of solvent and donor-acceptor arrangement on linear and nonlinear optical (NLO) response properties of two novel ICT-based fluorescent sensors, one consisting of hemicyanine and dimethylaniline as electron withdrawing and donating groups (molecule 1), respectively and its boron-dipyrromethene (BODIPY, molecule 2)-fused counterpart (molecule 3). Density functional theoretical (DFT) calculations using long-range corrected CAM-B3LYP and M06-2X functionals, suitable for studying properties of ICT molecules, are employed to calculate the desired properties. The dipole moment (µ) as well as the total first hyperpolarizability (β<sub>total</sub>) of the studied molecules in the gas phase is dominantly dictated by the component in the direction of charge transfer. The ratios of vector component of first hyperpolarizability (β<sub>vec</sub>) to β<sub>total</sub> also reveal unidirectional charge transfer process. The properties of the medium significantly affect the OPA, hyperpolarizability and TPA properties of the studied molecules. Time dependent DFT (TDDFT) calculations suggest interchanging between two lowest excited states of molecule 3 from the gas phase to salvation. The direction of charge polarization and dominant transitions among molecular orbitals involved in the OPA and TPA processes are studied. The results presented are expected to be useful in tuning the NLO response of many ICT-based chromophores, especially those with BODIPY acceptors.<br>

New two-photon absorption benzotriazole–coumarin dyads: the evidence of internal proton transfer in the excited state

2015 ◽  
Vol 56 (1) ◽  
pp. 236-242 ◽  
Author(s):  
Yulong Gong ◽  
Yao Lu ◽  
Zhenqiang Wang ◽  
Shengtao Zhang ◽  
Ziping Luo ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon

scholarly journals Polyfluorenylacetylene for near-infrared laser protection: polymer synthesis, optical limiting mechanism and relationship between molecular structure and properties

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53785-53796 ◽  
Author(s):  
Gang Zhao ◽  
Yan Feng ◽  
Shanyi Guang ◽  
Hongyao Xu ◽  
Naibo Lin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Near Infrared ◽  
Optical Limiting ◽  
High Thermal Stability ◽  
Photon Absorption ◽  
Structure And Properties ◽  
Absorption Mechanism ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Good Solubility

The incorporation of styryl/stilbene–fluorene into polyacetylenes not only endowed the polymers with novel near-infrared optical limiting properties based on a two-photon absorption mechanism but good solubility and high thermal stability.

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