Reactions of molybdenum cobalt clusters Cp'2Mo2Co2S3(CO)4 with nucleophiles: carbonyl substitution via cleavage of a cobalt-sulfur bond. Preparation and x-ray structure of Cp'2Mo2Co2S3(CO)4(PMe3)

Abstract(nC3H7)As(CN)2 (1) reacts with CO2(CO)8 (2) to yield the cluster 3 in which two (nC3H7)As fragments are coordinated to Co(CO)n (n = 1, 2, 3) groups. The cluster 3 has been characterizedby analytical and spectroscopic data and by an X -ray analysis.

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Phenyl complexes of ruthenium(II): competition between carbonyl substitution and formation of benzoyl complexes, and an X-ray study of a benzoyl complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9870000027 ◽

1987 ◽

pp. 27 ◽

Cited By ~ 6

Author(s):

Zbigniew Dauter ◽

Roger J. Mawby ◽

Colin D. Reynolds ◽

David R. Saunders ◽

Lars K. Hansen

Keyword(s):

X Ray ◽

Carbonyl Substitution

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Novel Intramolecular CAryl–S Bond Activation by an Electron Rich, Ring-Expanded-NHC-Rh centre: A Combined Experimental and DFT Study

Australian Journal of Chemistry ◽

10.1071/ch11243 ◽

2011 ◽

Vol 64 (8) ◽

pp. 1141 ◽

Cited By ~ 4

Author(s):

Abeer Binobaid ◽

Kingsley J. Cavell ◽

Mikhail S. Nechaev ◽

Benson M. Kariuki

Keyword(s):

Bond Activation ◽

Reaction Pathway ◽

Heterocyclic Carbenes ◽

Dft Study ◽

Dft Studies ◽

X Ray ◽

Carbene Complex ◽

Donor Capacity ◽

Insight Into ◽

Sulfur Bond

The reaction of (o-MeSPh)-N-functionalized tetrahydropyrimidinium salts with KN(SiMe3)2 and [Rh(COD)Cl]2 in THF leads to the formation of a novel dimeric RhIII bis-carbene complex. The reaction involves the unexpected cleavage/oxidative addition of the aryl-sulfur bond to give dimeric metallated RhIII with bridging MeS< moieties. This unusual reaction is probably a consequence of the sterically imposing structure and strong donor capacity of ring-expanded N-heterocyclic carbenes (RE-NHCs). An X-ray structure of the [(Ph,DIPP-NHC)Rh(Cl)(SMe)2] product complex has been obtained, and DFT studies were undertaken to gain an insight into the reaction pathway.

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Metallophosphoranes: Carbonyl substitution reactions and the X-ray crystal structure of cis-Cat2PMn(CO)4P(OPh)3 (Cat = benzodioxyl)

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(85)87450-7 ◽

1985 ◽

Vol 294 (3) ◽

pp. 347-355 ◽

Cited By ~ 6

Author(s):

Suman K. Chopra ◽

Shirley S.C. Chu ◽

Patrice De Meester ◽

Darren E. Geyer ◽

Michael Lattman ◽

...

Keyword(s):

Crystal Structure ◽

Substitution Reactions ◽

X Ray ◽

Carbonyl Substitution

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Darstellung, Schwingungsspektren und Röntgenstrukturanalyse von Trifluor- und Trichloracetyltrischwefeltrinitrid, CX3CO-NS3N21 / Synthesis, Vibrational Spectra, and X-ray Structure Analysis of Trifluoro and Trichloroacetyl Trisulfurtrinitride, CX3CO—NS3N21

Zeitschrift für Naturforschung B ◽

10.1515/znb-1977-0503 ◽

1977 ◽

Vol 32 (5) ◽

pp. 488-494 ◽

Cited By ~ 20

Author(s):

Ralf Steudel ◽

Fritz Rose ◽

Richard Reinhardt ◽

Hans Bradaczek

Keyword(s):

Acetic Acid ◽

Structure Analysis ◽

Multiple Bond ◽

Acid Anhydride ◽

Infrared And Raman Spectra ◽

X Ray ◽

Nitrogen Bonds ◽

The Relationship ◽

Sulfur Bond ◽

Exocyclic Nitrogen Atom

S4N4 reacts at 25 °C with trifluoro and trichloro acetic acid anhydride, respectively, to yield yellow crystalline CX3–CO–NS3N2 (X = F, Cl), the mass, infrared, and Raman spectra of which are reported. An X-ray structure analysis of monoclinic CF3CONS3N2 revealed a non-planar five-membered S3N2 ring containing an unusually long (2.206 A) sulfur-sulfur bond with one sulfur atom additionally connected to an exocyclic nitrogen atom by a multiple bond. Comparisons with the infrared spectra of S3N2O and ten compounds of type RNS3N2 allowed to identify four wavenumbers characteristic for the S3N2 ring. The relationship μ = 23.09d-27.27 has been derived for stretching vibrational wavelengths, μ (in μm), and bond distances, d (in Å), of sulfur-nitrogen bonds.

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