scholarly journals Interfacial charge separation in Cu2O/RuOx as a visible light driven CO2 reduction catalyst

2014 ◽  
Vol 16 (13) ◽  
pp. 5922-5926 ◽  
Author(s):  
Ernest Pastor ◽  
Federico M. Pesci ◽  
Anna Reynal ◽  
Albertus D. Handoko ◽  
Mingjia Guo ◽  
...  

Transient absorption spectroscopy as a tool to monitor charge carriers in Cu2O–RuOx photocathodes for CO2 reduction.

Author(s):  
Lianlian Peng ◽  
Shuqing Chang ◽  
Ziling Liu ◽  
Yanghe Fu ◽  
Rui Ma ◽  
...  

Compared to the electron-withdrawing groups, the electron-donating groups in TpBD can accelerate the photogenerated charge separation and transfer, thereby improving the photocatalytic performance for photocatalytic CO2 reduction.


Author(s):  
Akin Aydogan ◽  
Rachel Bangle ◽  
Simon De Kreijger ◽  
John Dickenson ◽  
Michael L Singleton ◽  
...  

The mechanism of a visible light-driven dehalogenation/cyclization reaction was investigated using ruthenium(II), iridium(III) and iron(III) photosensitizers by means of steady-state photoluminescence, time-resolved infrared spectroscopy, and nanosecond/femtosecond transient absorption spectroscopy. The...


Author(s):  
Elisabetta Benazzi ◽  
Joshua Karlsson ◽  
Youssef Ben M'Barek ◽  
Pavel Chabera ◽  
Sébastien Blanchard ◽  
...  

H+ modulated charge-transfer in photoexcited covalently linked W and Mo Keggin-bodipy conjugates is demonstrated using transient absorption spectroscopy and photoluminescence. Adding acid switches on (W) or accelerates (Mo) charge separation.


2015 ◽  
Vol 8 (9) ◽  
pp. 2713-2724 ◽  
Author(s):  
Joseph K. Gallaher ◽  
Shyamal K. K. Prasad ◽  
Mohammad A. Uddin ◽  
Taehyo Kim ◽  
Jin Young Kim ◽  
...  

Transient absorption spectroscopy reveals that the superior performance of three-versus two-phase polymer : fullerene blends is associated with hole migration from intermixed to pure polymer phases.


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