Evaluation of hydrogen and carbon monoxide mass transfer and a correlation between the myoglobin-protein bioassay and gas chromatography method for carbon monoxide determination

RSC Advances ◽  
2014 ◽  
Vol 4 (71) ◽  
pp. 37575-37581 ◽  
Author(s):  
Pradeep Chaminda Munasinghe ◽  
Samir Kumar Khanal
Keyword(s):  
Mass Transfer ◽  
Gas Chromatography ◽  
Carbon Monoxide ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Reliable Method ◽  
Volumetric Mass Transfer Coefficient ◽  
Syngas Fermentation ◽  
Chromatography Method ◽  
Gc Analysis

Myoglobin-protein bioassay, which is a much simpler, faster and cheaper method compared well with GC analysis, can be used as a reliable method of determining the volumetric mass transfer coefficient of CO in syngas fermentation studies.

scholarly journals Gas–liquid mass transfer characteristics of aviation fuel scrubbing in an aircraft fuel tank

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Li Chaoyue ◽  
Feng Shiyu ◽  
Xu Lei ◽  
Peng Xiaotian ◽  
Yan Yan
Keyword(s):  
Mass Transfer ◽  
Dissolved Oxygen ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Oxygen Concentration ◽  
Gas Holdup ◽  
Aviation Fuel ◽  
Volumetric Mass Transfer Coefficient ◽  
Dissolved Oxygen Concentration ◽  
Liquid Mass Transfer

AbstractDissolved oxygen evolving from aviation fuel leads to an increase in the oxygen concentration in an inert aircraft fuel tank ullage that may increase the flammability of the tank. Aviation fuel scrubbing with nitrogen-enriched air (NEA) can largely reduce the amount of dissolved oxygen and counteract the adverse effect of oxygen evolution. The gas–liquid mass transfer characteristics of aviation fuel scrubbing are investigated using the computational fluid dynamics method, which is verified experimentally. The effects of the NEA bubble diameter, NEA superficial velocity and fuel load on oxygen transfer between NEA and aviation fuel are discussed. Findings from this work indicate that the descent rate of the average dissolved oxygen concentration, gas holdup distribution and volumetric mass transfer coefficient increase with increasing NEA superficial velocity but decrease with increasing bubble diameter and fuel load. When the bubble diameter varies from 1 to 4 mm, the maximum change of descent rate of dissolved oxygen concentration is 18.46%, the gas holdup is 8.73%, the oxygen volumetric mass transfer coefficient is 81.45%. When the NEA superficial velocities varies from 0.04 to 0.10 m/s, the maximum change of descent rate of dissolved oxygen concentration is 146.77%, the gas holdup is 77.14%, the oxygen volumetric mass transfer coefficient is 175.38%. When the fuel load varies from 35 to 80%, the maximum change of descent rate of dissolved oxygen concentration is 21.15%, the gas holdup is 49.54%, the oxygen volumetric mass transfer coefficient is 44.57%. These results provide a better understanding of the gas and liquid mass transfer characteristics of aviation fuel scrubbing in aircraft fuel tanks and can promote the optimal design of fuel scrubbing inerting systems.

Mass Transfer Coefficients during Steel Decarburization in a RH Degasser

2008 ◽  
Vol 273-276 ◽  
pp. 679-684
Author(s):  
Roberto Parreiras Tavares ◽  
André Afonso Nascimento ◽  
Henrique Loures Vale Pujatti
Keyword(s):  
Mass Transfer ◽  
Reynolds Number ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Gas Flow ◽  
Vacuum Chamber ◽  
Volumetric Mass Transfer Coefficient ◽  
Gas Flow Rate ◽  
Rh Process ◽  
Kinetics Of

The RH process is a secondary refining process that can simultaneously attain significant levels of removal of interstitial elements, such as carbon, nitrogen and hydrogen, from liquid steel. In the RH process, the decarburization rate plays a very important role in determining the productivity of the equipment. The kinetics of this reaction is controlled by mass transfer in the liquid phase. In the present work, a physical model of a RH degasser has been built and used in the study of the kinetics of decarburization. The effects of the gas flow rate and of the configurations of the nozzles used in the injection of the gas have been analyzed. The decarburization reaction of liquid steel was simulated using a reaction involving CO2 and caustic solutions. The concentration of CO2 in the solution was evaluated using pH measurements. Based on the experimental results, it was possible to estimate the reaction rate constant. A volumetric mass transfer coefficient was then calculated based on these rate constants and on the circulation rate of the liquid. The logarithm of the mass transfer coefficient showed a linear relationship with the logarithm of the gas flow rate. The slope of the line was found to vary according to the relevance of the reaction at the free surface in the vacuum chamber. A linear relationship between the volumetric mass transfer coefficient and the nozzle Reynolds number was also observed. The slopes of the lines changed according to the relative importance of the two reaction sites, gas-liquid interface in the upleg snorkel and in the vacuum. At higher Reynolds number, the reaction in the vacuum chamber tends to be more significant.

Volumetric mass transfer coefficient in the fermenter agitated by Rushton turbines of various diameters in coalescent batch

2019 ◽  
Vol 130 ◽  
pp. 968-977 ◽  
Author(s):  
Radim Petříček ◽  
Tomáš Moucha ◽  
Tomáš Kracík ◽  
František Jonáš Rejl ◽  
Lukáš Valenz ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Volumetric Mass Transfer Coefficient
Sign in / Sign up

Export Citation Format

Share Document