Preparation of reduced graphene oxide/Cu nanoparticle composites through electrophoretic deposition: application for nonenzymatic glucose sensing

RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 15861-15869 ◽  
Author(s):  
Qian Wang ◽  
Qi Wang ◽  
Musen Li ◽  
Sabine Szunerits ◽  
Rabah Boukherroub

The paper reports on the simultaneous reduction/deposition of thin films of rGO/Cu NPs from an ethanol solution of GO and CuSO4 using EPD technique. The electrocatalytic properties of the electrode were exploited for non-enzymatic glucose sensing.

2016 ◽  
Vol 237 ◽  
pp. 693-701 ◽  
Author(s):  
Hakim Belkhalfa ◽  
Florina Teodorescu ◽  
Gurvan Quéniat ◽  
Yannick Coffinier ◽  
Nahed Dokhan ◽  
...  

2014 ◽  
Vol 2 (15) ◽  
pp. 5525-5533 ◽  
Author(s):  
Palaniappan Subramanian ◽  
Joanna Niedziolka-Jonsson ◽  
Adam Lesniewski ◽  
Qian Wang ◽  
Musen Li ◽  
...  

A sensitive and stable non-enzymatic sensing platform for d-glucose based on a reduced graphene oxide (rGO) matrix modified with Ni(OH)2 nanostructures was established.


Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 256
Author(s):  
Irina V. Pushkareva ◽  
Artem S. Pushkarev ◽  
Valery N. Kalinichenko ◽  
Ratibor G. Chumakov ◽  
Maksim A. Soloviev ◽  
...  

Platinum (Pt)-based electrocatalysts supported by reduced graphene oxide (RGO) were synthesized using two different methods, namely: (i) a conventional two-step polyol process using RGO as the substrate, and (ii) a modified polyol process implicating the simultaneous reduction of a Pt nanoparticle precursor and graphene oxide (GO). The structure, morphology, and electrochemical performances of the obtained Pt/RGO catalysts were studied and compared with a reference Pt/carbon black Vulcan XC-72 (C) sample. It was shown that the Pt/RGO obtained by the optimized simultaneous reduction process had higher Pt utilization and electrochemically active surface area (EASA) values, and a better performance stability. The use of this catalyst at the cathode of a proton exchange membrane fuel cell (PEMFC) led to an increase in its maximum power density of up to 17%, and significantly enhanced its performance especially at high current densities. It is possible to conclude that the optimized synthesis procedure allows for a more uniform distribution of the Pt nanoparticles and ensures better binding of the particles to the surface of the support. The advantages of Pt/RGO synthesized in this way over conventional Pt/C are the high electrical conductivity and specific surface area provided by RGO, as well as a reduction in the percolation limit of the components of the electrocatalytic layer due to the high aspect ratio of RGO.


2019 ◽  
Vol 3 (7) ◽  
pp. 1462-1470 ◽  
Author(s):  
Weiwei Wei ◽  
Rohit L. Vekariy ◽  
Chuanting You ◽  
Yafei He ◽  
Ping Liu ◽  
...  

Highly dense thin films assembled from cellulose nanofibers and reduced graphene oxide via van der Waals interactions to realize ultrahigh volumetric double-layer capacitances.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 623
Author(s):  
Monika Gupta ◽  
Huzein Fahmi Hawari ◽  
Pradeep Kumar ◽  
Zainal Arif Burhanudin ◽  
Nelson Tansu

The demand for carbon dioxide (CO2) gas detection is increasing nowadays. However, its fast detection at room temperature (RT) is a major challenge. Graphene is found to be the most promising sensing material for RT detection, owing to its high surface area and electrical conductivity. In this work, we report a highly edge functionalized chemically synthesized reduced graphene oxide (rGO) thin films to achieve fast sensing response for CO2 gas at room temperature. The high amount of edge functional groups is prominent for the sorption of CO2 molecules. Initially, rGO is synthesized by reduction of GO using ascorbic acid (AA) as a reducing agent. Three different concentrations of rGO are prepared using three AA concentrations (25, 50, and 100 mg) to optimize the material properties such as functional groups and conductivity. Thin films of three different AA reduced rGO suspensions (AArGO25, AArGO50, AArGO100) are developed and later analyzed using standard FTIR, XRD, Raman, XPS, TEM, SEM, and four-point probe measurement techniques. We find that the highest edge functionality is achieved by the AArGO25 sample with a conductivity of ~1389 S/cm. The functionalized AArGO25 gas sensor shows recordable high sensing properties (response and recovery time) with good repeatability for CO2 at room temperature at 500 ppm and 50 ppm. Short response and recovery time of ~26 s and ~10 s, respectively, are achieved for 500 ppm CO2 gas with the sensitivity of ~50 Hz/µg. We believe that a highly functionalized AArGO CO2 gas sensor could be applicable for enhanced oil recovery, industrial and domestic safety applications.


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