Synthesis and characterization of a phosphorus-containing flame retardant with double bonds and its application in bismaleimide resins

RSC Advances ◽  
2015 ◽  
Vol 5 (123) ◽  
pp. 101480-101486 ◽  
Author(s):  
Song Li ◽  
Hongxia Yan ◽  
Shuyao Feng ◽  
Song Niu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Synthesis And Characterization ◽  
Bismaleimide Resin ◽  
Phosphorus Containing ◽  
Reactive Phosphorus ◽  
Bismaleimide Resins

A novel reactive phosphorus-containing flame retardant was synthesized and used to modify bismaleimide resin. According to investigations, the modified bismaleimide resin has good mechanical properties, thermal stability and flame retardancy.

scholarly journals A bio-based phosphaphenanthrene-containing derivative modified epoxy thermosets with good flame retardancy, high mechanical properties and transparency

RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30943-30954
Author(s):  
Wei Peng ◽  
Yu-xuan Xu ◽  
Shi-bin Nie ◽  
Wei Yang
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Flame Retardants ◽  
The Past ◽  
Phosphorus Containing ◽  
Modified Epoxy

Phosphorus-containing flame retardants have received huge interest for improving the flame retardant behavior of epoxy resins (EP) over the past few decades.

scholarly journals Investigation of the Structure-Property Effect of Phosphorus-Containing Polysulfone on Decomposition and Flame Retardant Epoxy Resin Composites

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 380 ◽  
Author(s):  
Wei Zhao ◽  
Yongxiang Li ◽  
Qiushi Li ◽  
Yiliang Wang ◽  
Gong Wang
Keyword(s):  
Thermal Stability ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Phosphorus Content ◽  
Structure Property ◽  
Scanning Calorimetry ◽  
Inhibition Effect ◽  
Phosphorus Containing ◽  
High Degree ◽  
Thermal Stability Of

The flame retardant modification of epoxy (EP) is of great signification for aerospace, automotive, marine, and energy industries. In this study, a series of EP composites containing different variations of phosphorus-containing polysulfone (with a phosphorus content of approximately 1.25 wt %) were obtained. The obtained EP/polysulfone composites had a high glass transition temperature (Tg) and high flame retardancy. The influence of phosphorus-containing compounds (ArPN2, ArPO2, ArOPN2 and ArOPO2) on the thermal properties and flame retardancy of EP/polysulfone composites was investigated by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), a UL-94 vertical burning test, and cone calorimeter tests. The phosphorus-containing polysulfone enhanced the thermal stability of EP. The more stable porous char layer, less flammable gases, and a lower apparent activation energy at a high degree of conversion demonstrated the high gas inhibition effect of phosphorus-containing compounds. Moreover, the gas inhibition effect of polysulfone with a P–C bond was more efficient than the polysulfone with a P–O–C bond. The potential for optimizing flame retardancy while maintaining a high Tg is highlighted in this study. The flame-retardant EP/polysulfone composites with high thermal stability broaden the application field of epoxy.

scholarly journals Highly Efficient Composite Flame Retardants for Improving the Flame Retardancy, Thermal Stability, Smoke Suppression, and Mechanical Properties of EVA

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1251
Author(s):  
Yilin Liu ◽  
Bin Li ◽  
Miaojun Xu ◽  
Lili Wang
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Heat Release ◽  
Flame Retardant ◽  
Production Rate ◽  
Flame Retardancy ◽  
Flame Retardants ◽  
Mass Loss Rate ◽  
Smoke Suppression ◽  
Average Mass

Ethylene vinyl acetate (EVA) copolymer has been used extensively in many fields. However, EVA is flammable and releases CO gas during burning. In this work, a composite flame retardant with ammonium polyphosphate (APP), a charring–foaming agent (CFA), and a layered double hydroxide (LDH) containing rare-earth elements (REEs) was obtained and used to improve the flame retardancy, thermal stability, and smoke suppression for an EVA matrix. The thermal analysis showed that the maximum thermal degradation temperature of all composites increased by more than 37 °C compared with that of pure EVA. S-LaMgAl/APP/CFA/EVA, S-CeMgAl/APP/CFA/EVA, and S-NdMgAl/APP/CFA/EVA could achieve self-extinguishing behavior according to the UL-94 tests (V-0 rating). The peak heat release rate (pk-HRR) indicated that all LDHs containing REEs obviously reduced the fire strength in comparison with S-MgAl. In particular, pk-HRR of S-LaMgAl/APP/CFA/EVA, S-CeMgAl/APP/CFA/EVA and S-NdMgAl/APP/CFA/EVA were all decreased by more than 82% in comparison with pure EVA. Furthermore, the total heat release (THR), smoke production rate (SPR), and production rate of CO (COP) also decreased significantly. The average mass loss rate (AMLR) confirmed that the flame retardant exerted an effect in the condensed phase of the composites. Meanwhile, the combination of APP, CFA, and LDH containing REEs allowed the EVA matrix to maintain good mechanical properties.

Phosphorus-containing flame-retardant bismaleimide resin with high mechanical properties

2016 ◽  
Vol 73 (12) ◽  
pp. 3547-3557 ◽  
Author(s):  
Song Li ◽  
Hongxia Yan ◽  
Shuyao Feng ◽  
Xu Li
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Bismaleimide Resin ◽  
Phosphorus Containing

Synthesis and characterization of novel phosphorous-silicone-nitrogen flame retardant and evaluation of its flame retardancy for epoxy thermosets

2014 ◽  
Vol 131 (24) ◽  
pp. n/a-n/a ◽  
Author(s):  
Zhi-Sheng Li ◽  
Jin-Gang Liu ◽  
Tao Song ◽  
Deng-Xiong Shen ◽  
Shi-Yong Yang
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Synthesis And Characterization

Study on the Synthesis and Characterization of a Novel Phosphorus-Nitrogen Containing Intumescent Flame Retardant

2011 ◽  
Vol 399-401 ◽  
pp. 1376-1380
Author(s):  
Li Hua You ◽  
Yin Yin Hui ◽  
Xiang Ning Shi ◽  
Zhi Han Peng
Keyword(s):  
Molecular Structure ◽  
Thermal Properties ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Oxygen Index ◽  
Phosphinic Acid ◽  
Intumescent Flame Retardant ◽  
Synthesis And Characterization ◽  
Limiting Oxygen Index

In this study, a novel phosphorus-nitrogen containing intumescent flame retardant (P-N IFR) poly(melamine 2-carboxyethyl(phenyl) phosphate)(PMCEP) was prepared via the reaction of 2-carboxyethyl (phenyl) phosphinic acid (CEPPA) and melamine (MEL) in two-steps. Meanwhile, the molecular structure of the chemical compound was determined by FTIR,1H-NMR and elemental analysis; and the thermal properties was investigated by means of TGA. Combustion studies revealed high limiting oxygen index (LOI) indicative of better flame-retardancy properties for PBT resin.

Synthesis and characterization of a novel organophosphorus oligomer and its application in improving flame retardancy of epoxy resin

RSC Advances ◽  
2014 ◽  
Vol 4 (34) ◽  
pp. 17607-17614 ◽  
Author(s):  
Nana Tian ◽  
Jiang Gong ◽  
Xin Wen ◽  
Kun Yao ◽  
Tao Tang
Keyword(s):  
Thermal Stability ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Synthesis And Characterization

A novel organophosphorus oligomer (PCPBO) was synthesized and the incorporation of PCPBO into epoxy resin (EP) significantly improved their flame retardancy and thermal stability.

Synthesis, Characterization and Flame Retardancy of Two Novels Amino Phosphate

2012 ◽  
Vol 554-556 ◽  
pp. 110-114
Author(s):  
Da Ming Ban ◽  
Yang Min ◽  
Yong Hang Zhang ◽  
Ou Zhao
Keyword(s):  
Thermal Stability ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Flame Retardant ◽  
Elemental Analysis ◽  
Flame Retardancy ◽  
Spectroscopic Data ◽  
Polyamide 6 ◽  
Phosphorus Containing ◽  
Thermal Stability Of

Two phosphorus-containing flame retardant (FR) were synthesized and incorporated in the backbone of polyamide 6(PA6) by polymerization. The structure and spectroscopic data of these flame retardant were determined by Fourier Transform Infrared Spectroscopy (FTIR) and Elemental analysis. Flame-retardancy and thermal property of PA6 modified with CEP, and MMP were examined by LOI and TGA. The LOI value of PA6 shows ascending trend by adding FRs, and it rise from 24 to 31%. TGA data revealed that FR improves thermal stability of PA6. The on-set temperature was added at least 20°C.

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