Applications and stereoselective syntheses of P-chirogenic phosphorus compounds

2016 ◽  
Vol 45 (20) ◽  
pp. 5771-5794 ◽  
Author(s):  
Mathieu Dutartre ◽  
Jérôme Bayardon ◽  
Sylvain Jugé
Keyword(s):  
Building Blocks ◽  
Phosphorus Compound ◽  
Phosphorus Compounds ◽  
Asymmetric Syntheses ◽  
Review Reports ◽  
Stereoselective Syntheses

This review reports the best stereoselective or asymmetric syntheses, the most efficient P*-building blocks and functionalisation of P-chirogenic compounds, in the light of chiral phosphorus compound applications.

scholarly journals Wine By-Products as Raw Materials for the Production of Biopolymers and of Natural Reinforcing Fillers: A Critical Review

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 381
Author(s):  
Alessandro Nanni ◽  
Mariafederica Parisi ◽  
Martino Colonna
Keyword(s):  
Critical Review ◽  
Raw Materials ◽  
Green Revolution ◽  
Building Blocks ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Reinforcing Fillers ◽  
Plastic Industry ◽  
Review Reports ◽  
By Products

The plastic industry is today facing a green revolution; however, biopolymers, produced in low amounts, expensive, and food competitive do not represent an efficient solution. The use of wine waste as second-generation feedstock for the synthesis of polymer building blocks or as reinforcing fillers could represent a solution to reduce biopolymer costs and to boost the biopolymer presence in the market. The present critical review reports the state of the art of the scientific studies concerning the use of wine by-products as substrate for the synthesis of polymer building blocks and as reinforcing fillers for polymers. The review has been mainly focused on the most used bio-based and biodegradable polymers present in the market (i.e., poly(lactic acid), poly(butylene succinate), and poly(hydroxyalkanoates)). The results present in the literature have been reviewed and elaborated in order to suggest new possibilities of development based on the chemical and physical characteristics of wine by-products.

Enantiopure Cyclic Nitrones: A Useful Class of Building Blocks for Asymmetric Syntheses

Synthesis ◽  
2007 ◽  
Vol 2007 (04) ◽  
pp. 485-504 ◽  
Author(s):  
Alberto Brandi ◽  
Julia Revuelta ◽  
Stefano Cicchi ◽  
Andrea Goti
Keyword(s):  
Building Blocks ◽  
Asymmetric Syntheses ◽  
Cyclic Nitrones

ChemInform Abstract: Applications and Stereoselective Syntheses of P-Chirogenic Phosphorus Compounds

ChemInform ◽  
2016 ◽  
Vol 47 (49) ◽  
Author(s):  
Mathieu Dutartre ◽  
Jerome Bayardon ◽  
Sylvain Juge
Keyword(s):  
Phosphorus Compounds ◽  
Stereoselective Syntheses

scholarly journals Mixed-Oxide Catalysts with Spinel Structure for the Valorization of Biomass: The Chemical-Loop Reforming of Bioethanol

Catalysts ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 332 ◽  
Author(s):  
Olena Vozniuk ◽  
Tommaso Tabanelli ◽  
Nathalie Tanchoux ◽  
Jean-Marc Millet ◽  
Stefania Albonetti ◽  
...  
Keyword(s):  
Solid State ◽  
Spinel Structure ◽  
Mixed Oxides ◽  
Building Blocks ◽  
Short Review ◽  
Solid State Chemistry ◽  
Spinel Type ◽  
Mixed Oxide Catalysts ◽  
Versatile Tool ◽  
Review Reports

This short review reports on spinel-type mixed oxides as catalysts for the transformation of biomass-derived building blocks into chemicals and fuel additives. After an overview of the various methods reported in the literature for the synthesis of mixed oxides with spinel structure, the use of this class of materials for the chemical-loop reforming of bioalcohols is reviewed in detail. This reaction is aimed at the production of H2 with intrinsic separation of C-containing products, but also is a very versatile tool for investigating the solid-state chemistry of spinels.

scholarly journals Preparation and properties of flame-retardant epoxy resins containing reactive phosphorus flame retardant

2020 ◽  
Vol 15 ◽  
pp. 155892502090132
Author(s):  
Sang-Hoon Lee ◽  
Seung-Won Oh ◽  
Young-Hee Lee ◽  
Il-Jin Kim ◽  
Dong-Jin Lee ◽  
...  
Keyword(s):  
Impact Strength ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Phosphorus Content ◽  
Phosphorus Compound ◽  
Phosphorus Compounds ◽  
Limiting Oxygen Index ◽  
The Impact

To prepare flame-retardant epoxy resin, phosphorus compound containing di-hydroxyl group (10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ) was reacted with uncured epoxy resin (diglycidyl ether of bisphenol A, YD-128) and then cured using a curing agent (dicyandiamide, DICY). This study focused on the effect of phosphorus compound/phosphorus content on physical properties and flame retardancy of cured epoxy resin. The thermal decomposition temperature of the cured epoxy resins (samples: P0, P1.5, P2.0, and P2.5, the number represents the wt% of phosphorus) increased with increasing the content of phosphorus compound/phosphorus (0/0, 19.8/1.5, 27.8/2.0, and 36.8/2.5 wt%) based on epoxy resin. The impact strength of the cured epoxy resin increased significantly with increasing phosphorus compound content. As the phosphorus compound/phosphorus content increased from 0/0 to 36.8/2.5 wt%, the glass transition temperature (the peak temperature of loss modulus curve) increased from 135.2°C to 142.0°C. In addition, as the content of phosphorous compound increased, the storage modulus remained almost constant up to higher temperature. The limiting oxygen index value of cured epoxy resin increased from 21.1% to 30.0% with increasing phosphorus compound/phosphorus content from 0/0 to 36.8/2.5 wt%. The UL 94 V test result showed that no rating for phosphorus compounds less than 19.8 wt% and V-1 for 27.8 wt%. However, when the phosphorus compound was 36.8 wt%, the V-0 level indicating complete flame retardancy was obtained. In conclusion, the incorporation of phosphorus compounds into the epoxy chain resulted in improved properties such as impact strength and heat resistance, as well as a significant increase in flame retardancy.

Stereoselective Syntheses of the 2-Isopropenyl-2,3-dihydrobenzofuran Nucleus:  Potential Chiral Building Blocks for the Syntheses of Tremetone, Hydroxytremetone, and Rotenone

2007 ◽  
Vol 72 (8) ◽  
pp. 2857-2864 ◽  
Author(s):  
Stephen C. Pelly ◽  
Sameshnee Govender ◽  
Manuel A. Fernandes ◽  
Hans-Günther Schmalz ◽  
Charles B. de Koning
Keyword(s):  
Building Blocks ◽  
Stereoselective Syntheses

scholarly journals Mechanically axially chiral catenanes and noncanonical chiral rotaxanes

2021 ◽  
Author(s):  
John Maynard ◽  
Peter Gallagher ◽  
David Lozano ◽  
Patrick Butler ◽  
Steve Goldup
Keyword(s):  
Building Blocks ◽  
Biological Properties ◽  
Mirror Image ◽  
Chiral Structure ◽  
Molecular Chirality ◽  
Symmetry Properties ◽  
Axially Chiral ◽  
A Chain ◽  
Stereoselective Syntheses ◽  
Molecular Rings

Chirality, the property of objects that are distinct from their own mirror image, is important in many scientific areas but particularly chemistry, where the appearance of molecular chirality because of rigid arrangements of atoms in space famously influences a molecule’s biological properties. Less generally appreciated is that two molecular rings with chemically distinct faces combined like links in a chain results in a chiral structure even when the rings are achiral. To date, no enantiopure examples of such mechanically axially chiral catenanes has been reported. We re-examined the symmetry properties of the mechanically axially chiral motif and identified a straightforward route to such molecules from simple building blocks. We also identify that common representations of axially chiral catenanes obscure that a previously overlooked stereogenic unit arises when a ring is threaded onto a dumbbell-shaped molecule to generate a rotaxane. These insights allowed us to demonstrate the first stereoselective syntheses of an axially chiral catenane and a noncanonical axially chiral rotaxane motif. With methods to access these structures in hand, the process of exploring their properties and applications can now begin.

scholarly journals Mechanically axially chiral catenanes and noncanonical chiral rotaxanes

2021 ◽  
Author(s):  
John Maynard ◽  
Peter Gallagher ◽  
David Lozano ◽  
Patrick Butler ◽  
Steve Goldup
Keyword(s):  
Building Blocks ◽  
Biological Properties ◽  
Mirror Image ◽  
Chiral Structure ◽  
Molecular Chirality ◽  
Symmetry Properties ◽  
Axially Chiral ◽  
A Chain ◽  
Stereoselective Syntheses ◽  
Molecular Rings

Chirality, the property of objects that are distinct from their own mirror image, is important in many scientific areas but particularly chemistry, where the appearance of molecular chirality because of rigid arrangements of atoms in space famously influences a molecule’s biological properties. Less generally appreciated is that two molecular rings with chemically distinct faces combined like links in a chain results in a chiral structure even when the rings are achiral. To date, no enantiopure examples of such mechanically axially chiral catenanes has been reported. We re-examined the symmetry properties of the mechanically axially chiral motif and identified a straightforward route to such molecules from simple building blocks. We also identify that common representations of axially chiral catenanes obscure that a previously overlooked stereogenic unit arises when a ring is threaded onto a dumbbell-shaped molecule to generate a rotaxane. These insights allowed us to demonstrate the first stereoselective syntheses of an axially chiral catenane and a noncanonical axially chiral rotaxane motif. With methods to access these structures in hand, the process of exploring their properties and applications can now begin.

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