Cobalt-doped graphitic carbon nitride with enhanced peroxidase-like activity for wastewater treatment

RSC Advances ◽  
2016 ◽  
Vol 6 (42) ◽  
pp. 35568-35576 ◽  
Author(s):  
Jianshuai Mu ◽  
Jie Li ◽  
Xin Zhao ◽  
En-Cui Yang ◽  
Xiao-Jun Zhao
Keyword(s):  
Wastewater Treatment ◽  
Carbon Nitride ◽  
Degradation Rate ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Cobalt Doping

The peroxidase-like activity of graphitic carbon nitride (g-C3N4) is dramatically increased by a small cobalt doping. The cobalt-doped g-C3N4 was used for wastewater treatment, exhibiting much higher degradation rate than that of pure g-C3N4.

scholarly journals Investigation of Fe-Doped Graphitic Carbon Nitride-Silver Tungstate as a Ternary Visible Light Active Photocatalyst

2021 ◽  
Vol 2021 ◽  
pp. 1-18
Author(s):  
Eid H. Alosaimi ◽  
Nadia Azeem ◽  
Noor Tahir ◽  
Asim Jilani ◽  
Muhammad Zahid ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Visible Light ◽  
Metal Oxides ◽  
Advanced Oxidation Processes ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Oxidation Processes ◽  
Visible Light Active ◽  
Silver Tungstate

The rapid population growth and economic development have largely contributed to environmental pollution. Various advanced oxidation processes have been used as the most viable solution for the reduction of recalcitrant pollutants and wastewater treatment. Heterogeneous photocatalysis is one of the broadly used technologies for wastewater treatment among all advanced oxidation processes. Graphitic carbon nitride alone or in combination with various other semiconductor metal oxide materials acts as a competent visible light active photocatalyst for the removal of recalcitrant organic pollutants from wastewater. Rational designing of an environment-friendly photocatalyst through a facile synthetic approach encounters various challenges in photocatalytic technologies dealing with semiconductor metal oxides. Doping in g-C3N4 and subsequent coupling with metal oxides have shown remarkable enhancement in the photodegradation activity of g-C3N4-based nanocomposites owing to the modulation in g-C3N4 bandgap structuring and surface area. In the current study, a novel ternary Fe-doped g-C3N4/Ag2WO4 visible light active photocatalyst was fabricated through an ultrasonic-assisted facile hydrothermal method. Characterization analysis included SEM analysis, FTIR, XRD, XPS, and UV-Visible techniques to elucidate the morphology and chemical structuring of the as-prepared heterostructure. The bandgap energies were assessed using the Tauc plot. The ternary nanocomposite (Fe-CN-AW) showed increased photodegradation efficiency (97%) within 120 minutes, at optimal conditions of pH = 8, catalyst dose = 50 mg/100 ml, an initial RhB concentration of 10 ppm, and oxidant dose 5 mM under sunlight irradiation. The enhanced photodegradation of rhodamine B dye by ternary Fe-CN-AW was credited to multielectron transfer pathways due to insertion of a Fe dopant in graphitic carbon nitride and subsequent coupling with silver tungstate. The data were statistically assessed by the response surface methodology.

scholarly journals Photocatalytic Treatment of Pharmaceuticals in Real Hospital Wastewaters for Effluent Quality Amelioration

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2165 ◽  
Author(s):  
Konstas ◽  
Kosma ◽  
Konstantinou ◽  
Albanis
Keyword(s):  
Mass Spectrometry ◽  
Wastewater Treatment ◽  
Liquid Chromatography ◽  
High Resolution ◽  
Carbon Nitride ◽  
High Resolution Mass Spectrometry ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Hospital Wastewater ◽  
Resolution Mass

The presence of pharmaceutically active compounds (PhACs) in the wastewater effluents has confirmed that conventional wastewater treatment technologies are not sufficiently effective in the pharmaceuticals’ removal. The objective of the present study was to evaluate and compare the photocatalytic degradation of PhACs using TiO2-P25, graphitic carbon nitride (g-C3N4, CN) and a heterojunction of perovskite strodium titanate and graphitic carbon nitride SrTiO3/g-C3N4 (20% g-C3N4, 20CNSTO) photocatalytic materials, in hospital wastewater effluents, by simulated solar irradiation. The experiments were performed by using real wastewater samples collected from the university hospital wastewater treatment plant (WWTP) effluent of Ioannina city (Northwestern Greece) and inherent pharmaceutical concentration levels. The analysis of the samples was accomplished by solid phase extraction followed by liquid chromatography-Orbitrap high-resolution mass spectrometry. In the cases of TiO2 and CN, more than 70% of the initial concentration (e.g., venlafaxine) was degraded after 90 min, while 20CNSTO presented lower photocatalytic performance. Furthermore, some compounds were sporadically detected (e.g., fluoxetine) or their concentrations remained stable during the photocatalytic treatment time period (e.g., trimethoprim). In total 11 transformation products (TPs) were formed along the degradation processes and were identified by using liquid chromatography high resolution mass spectrometry.

Effect of cobalt doping into graphitic carbon nitride on photo induced removal of dye from water

2017 ◽  
Vol 89 ◽  
pp. 170-179 ◽  
Author(s):  
D. Das ◽  
D. Banerjee ◽  
B. Das ◽  
N.S. Das ◽  
K.K. Chattopadhyay
Keyword(s):  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Cobalt Doping

scholarly journals Preparation, Characterization of Graphitic Carbon Nitride Photo-Catalytic Nanocomposites and Their Application in Wastewater Remediation: A Review

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 723
Author(s):  
Caifang Li ◽  
Xianliang Wu ◽  
Junyue Shan ◽  
Jing Liu ◽  
Xianfei Huang
Keyword(s):  
Wastewater Treatment ◽  
Carbon Nitride ◽  
Electronic Energy ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Wastewater Remediation ◽  
Graphite Phase ◽  
Survival And Development ◽  
Physical And Chemical

Energy crisis and environmental pollution are the major problems of human survival and development. Photocatalytic technology can effectively use solar energy and is prospective to solve the above-mentioned problems. Carbon nitride is a two-dimensional polymer material with a graphite-like structure. It has good physical and chemical stabilities, unique chemical and electronic energy band structures, and is widely used in the field of photocatalysis. Graphitic carbon nitride has a conjugated large π bond structure, which is easier to be modified with other compounds. thereby the surface area and visible light absorption range of carbon nitride-based photocatalytic composites can be insignificantly increased, and interface electron transmission and corresponding photogenerated carriers separation of streams are simultaneously promoted. Therefore, the present study systematically introduced the basic catalytic principles, preparation and modification methods, characterization and calculation simulation of carbon nitride-based photocatalytic composite materials, and their application in wastewater treatment. We also summarized their application in wastewater treatment with the aid of artificial intelligence tools. This review summarized the frontier technology and future development prospects of graphite phase carbon nitride photocatalytic composites, which provide a theoretical reference for wastewater purification.

scholarly journals Fabrication of Polyethersulfone (PES) Membrane Incorporated with Graphitic Carbon Nitride (g-C3N4) Nanoparticles in Palm Oil Mill Effluent (POME) Wastewater Treatment

2021 ◽  
Vol 945 (1) ◽  
pp. 012053
Author(s):  
Cheong Kin Wai ◽  
Leong Kah Hon ◽  
Ling Wong Yong
Keyword(s):  
Wastewater Treatment ◽  
Carbon Nitride ◽  
Removal Rate ◽  
Sem Analysis ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Additive Concentration ◽  
Nanoparticles Concentration ◽  
Palm Oil Mill ◽  
Pes Membrane

Abstract Backed by the evolution in the nanotechnology field, membrane modified with nanoparticles as an additive has become increasingly prominent nowadays. The enormous potential of graphitic carbon nitride (g-C3N4) photocatalyst in wastewater treatment has been disclosed extensively. In this study, 4 Polyethersulfone (PES) membranes with different concentration of g-C3N4nanoparticles as additive were fabricated and their performances were investigated. Scanning Electron Microscopy (SEM) analysis showed that the membrane top surface layer was getting denser with the higher g-C3N4nanoparticles concentration which subsequently decreased the membrane mean pore size, porosity and flux. However the membrane with higher additive concentration was demonstrated a better improvement in anti-fouling properties where the flux recovery ratio (FRR) of the membranes showed an uptrend movement from 23.43% (membrane without additive) to 64.64% (membrane with 6 wt.% of additive). The enhancement of COD and colour removal rate from 61.50 % to 66.50 % and 78.75 % to 83.75 % was also observed in this study where the finding has signified the increased g-C3N4 nanoparticles concentration was constructive in PES membrane modification.

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