scholarly journals Dynamic covalent chemistry of imine polymers at the liquid/solid interface investigated by scanning tunneling microscopy

RSC Advances ◽  
2017 ◽  
Vol 7 (19) ◽  
pp. 11496-11502 ◽  
Author(s):  
Yanxia Yu ◽  
Jianbin Lin ◽  
Shengbin Lei
Keyword(s):  
Scanning Tunneling Microscopy ◽  
Fundamental Importance ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Dynamic Covalent Chemistry ◽  
Solid Interface ◽  
Adaptive Materials

How a dynamic covalent library adapts to the presence of a surface is of fundamental importance for the design of adaptive materials. Our investigation demonstrates that the surface markedly rearrange the composition of the DCC libraries.

Scanning Tunneling Microscopy and Spectroscopy of Donor-Acceptor-Donor Triads at the Liquid/Solid Interface

ChemPhysChem ◽  
2005 ◽  
Vol 6 (11) ◽  
pp. 2389-2395 ◽  
Author(s):  
Hiroshi Uji-i ◽  
Atsushi Miura ◽  
Albert Schenning ◽  
E. W. Meijer ◽  
Zhijian Chen ◽  
...  
Keyword(s):  
Scanning Tunneling Microscopy ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Solid Interface ◽  
Donor Acceptor

Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

2014 ◽  
Vol 50 (80) ◽  
pp. 11903-11906 ◽  
Author(s):  
Zongxia Guo ◽  
Inge De Cat ◽  
Bernard Van Averbeke ◽  
Jianbin Lin ◽  
Guojie Wang ◽  
...  
Keyword(s):  
Scanning Tunneling Microscopy ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Self Assembled Monolayer ◽  
Multicomponent Adsorption ◽  
Solid Interface ◽  
Apparent Reduction ◽  
Self Assembled

Here we report on the apparent reduction in surface chirality upon co-assembling a chiral and achiral molecule into a physisorbed self-assembled monolayer at the liquid/solid interface as revealed by scanning tunneling microscopy (STM).

Molecularly tuned peptide assemblies at the liquid–solid interface studied by scanning tunneling microscopy

2010 ◽  
Vol 12 (37) ◽  
pp. 11683 ◽  
Author(s):  
Lin Niu ◽  
Xiaojing Ma ◽  
Lei Liu ◽  
Xiaobo Mao ◽  
Dongxia Wu ◽  
...  
Keyword(s):  
Scanning Tunneling Microscopy ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Solid Interface

Supramolecular Chemistry at the Liquid/Solid Interface a Scanning Tunneling Microscopy Approach

2007 ◽  
Vol 121-123 ◽  
pp. 369-372
Author(s):  
S. de Feyter ◽  
A. Miura ◽  
H. Uji-i ◽  
P. Jonkheijm ◽  
A.P.H.J. Schenning ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Scanning Tunneling Microscopy ◽  
Supramolecular Chemistry ◽  
Organic Molecules ◽  
Molecular Conformation ◽  
Scanning Tunneling ◽  
Conjugated Oligomers ◽  
Two Dimensional ◽  
Tunneling Microscopy ◽  
Solid Interface

With scanning tunneling microscopy (STM), the intramolecular conformational and intermolecular ordering aspects have been investigated of a variety of organic molecules physisorbed at the liquid-solid interface. By balancing the interplay between intramolecular and intermolecular interactions (hydrogen bonding), leading to control of the molecular conformation, foldamers were created which order into well-defined two-dimensional crystals. The nature of the hydrogen bonding groups in conjugated oligomers leads to the formation of infinite stacks and cyclic multimers, expressing the chiral nature of the molecules.

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