scholarly journals Porous metalloporphyrinic nanospheres constructed from metal 5,10,15,20-tetraksi(4′-ethynylphenyl)porphyrin for efficient catalytic degradation of organic dyes

RSC Advances ◽  
2018 ◽  
Vol 8 (14) ◽  
pp. 7330-7339 ◽  
Author(s):  
Yongjin Li ◽  
Liming Wang ◽  
Yong Gao ◽  
Weijun Yang ◽  
Yingying Li ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Organic Dyes ◽  
Coupling Reaction ◽  
Catalytic Degradation ◽  
Sonogashira Coupling ◽  
Catalytic Activities ◽  
Sonogashira Coupling Reaction

A kind of novel conjugated metalloporphyrin polymers were synthesized by the Sonogashira coupling reaction. They were microporous nanospherical polymers and showed excellent catalytic activities and reusability in degradation of methylene blue.

scholarly journals Tetradentate Palladium(II) Salophen Complexes: Synthesis, Characterization and Catalytic Activities in Copper-Free Sonogashira Coupling Reaction

2018 ◽  
Vol 7 (3.11) ◽  
pp. 15 ◽  
Author(s):  
Shahrul Nizam Ahmad ◽  
Hadariah Bahron ◽  
Amalina Mohd Tajuddin
Keyword(s):  
Condensation Reaction ◽  
Coupling Reaction ◽  
13C Nmr Spectroscopy ◽  
Insertion Reaction ◽  
Catalyst Loading ◽  
Sonogashira Coupling ◽  
1H And 13C Nmr ◽  
Catalytic Activities ◽  
Sonogashira Coupling Reaction

This paper reports the synthesis and characterization of three salophen ligands; 2,2'-((1E,1'E)-(1,2 phenylenebis(azanylylidene))bis(methanylylidene))diphenol [L1H], 2,2'-((1E,1'E)-(1,2-phenylenebis(azanylylidene))bis (methanylylidene))bis(4-chlorophenol) [L1C] and 2,2'-((1E,1'E)-(1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-methoxylphenol) [L1OME]. The compounds were prepared from condensation reaction between salicylaldehyde, and its derivatives, with ortho-phenylenediamine. Their palladium(II) complexes, namely PdL1H, PdL1C and PdL1OME were synthesized through insertion reaction between the ligands with palladium(II) acetate. All compounds were characterized through melting point, elemental analysis, infrared spectroscopy, 1H and 13C NMR spectroscopy. Palladium(II) complexes were tested as homogenous catalysts in copper-free Sonogashira coupling reaction between iodobenzene and phenylacetylene in DMSO using triethylamine as base with 1.0 mmol% catalyst loading. The most performing catalyst was PdL1OME with 91% conversion followed by PdL1H (83%) and PdL1C (27%).   

ChemInform Abstract: 2,5-Bis(2-(diphenylphosphino)phenyl)-1,3,4-oxadiazole Ligands and Their Cu(I) Complexes for Sonogashira Coupling Reaction.

ChemInform ◽  
2014 ◽  
Vol 45 (35) ◽  
pp. no-no
Author(s):  
Cai-Xia Lin ◽  
Jia-Fang Zhu ◽  
Qing-Shan Li ◽  
Li-Hua Ao ◽  
Yan-Juan Jin ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Sonogashira Coupling Reaction

scholarly journals The Utility of Sonogashira Coupling Reaction for the Derivatization of Aryl Halides with Fluorescent Alkyne

2018 ◽  
Vol 34 (10) ◽  
pp. 1183-1188 ◽  
Author(s):  
Naoyuki YASAKA ◽  
Naoya KISHIKAWA ◽  
Takumi HIGASHIJIMA ◽  
Kaname OHYAMA ◽  
Naotaka KURODA
Keyword(s):  
Coupling Reaction ◽  
Aryl Halides ◽  
Sonogashira Coupling ◽  
Sonogashira Coupling Reaction

scholarly journals Synthesis of 9-arylalkynyl- and 9-aryl-substituted benzo[b]quinolizinium derivatives by Palladium-mediated cross-coupling reactions

2018 ◽  
Vol 14 ◽  
pp. 1871-1884 ◽  
Author(s):  
Siva Sankar Murthy Bandaru ◽  
Darinka Dzubiel ◽  
Heiko Ihmels ◽  
Mohebodin Karbasiyoun ◽  
Mohamed M A Mahmoud ◽  
...  
Keyword(s):  
Emission Intensity ◽  
Binding Constants ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Sonogashira Coupling ◽  
Reaction Conditions ◽  
Quadruplex Dna ◽  
Cross Coupling Reactions ◽  
Sonogashira Coupling Reaction

9-Arylbenzo[b]quinolizinium derivatives were prepared with base-free Suzuki–Miyaura coupling reactions between benzo[b]quinolizinium-9-trifluoroborate and selected benzenediazonium salts. In addition, the Sonogashira coupling reaction between 9-iodobenzo[b]quinolizinium and the arylalkyne derivatives yielded four novel 9-(arylethynyl)benzo[b]quinolizinium derivatives under relatively mild reaction conditions. The 9-(N,N-dimethylaminophenylethynyl)benzo[b]quinolizinium is only very weakly emitting, but the emission intensity increases by a factor >200 upon protonation, so that this derivative may operate as pH-sensitive light-up probe. Photometric and fluorimetric titrations of duplex and quadruplex DNA to 9-(arylethynyl)benzo[b]quinolizinium derivatives revealed a significant binding affinity of these compounds towards both DNA forms with binding constants ofKb= 0.2–2.2 × 105M−1.

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