Hybrid energy storage of battery-type nickel hydroxide and supercapacitor-type graphene: redox additive and charge storage mechanism

2017 ◽  
Vol 1 (2) ◽  
pp. 275-279 ◽  
Author(s):  
Pichamon Sirisinudomkit ◽  
Pawin Iamprasertkun ◽  
Atiweena Krittayavathananon ◽  
Tanut Pettong ◽  
Peerapan Dittanet ◽  
...  
Keyword(s):  
Energy Storage ◽  
Charge Storage ◽  
X Ray ◽  
Hybrid Energy ◽  
Storage Mechanism ◽  
Hybrid Energy Storage ◽  
Charge Storage Mechanism ◽  
X Ray Absorption ◽  
Type Nickel

Charge storage mechanism by in situ X-ray absorption spectroscopy.

The supercapacitor electrode properties and energy storage mechanism of binary transition metal sulfide MnCo2S4 compared with oxide MnCo2O4 studied using in situ quick X-ray absorption spectroscopy

2021 ◽  
Author(s):  
Su-Yang Hsu ◽  
Feng-Hao Hsu ◽  
Jeng-Lung Chen ◽  
Yu-Song Cheng ◽  
Jin-Ming Chen ◽  
...  
Keyword(s):  
Fine Structure ◽  
Energy Storage ◽  
Transition Metal ◽  
Metal Sulfide ◽  
Supercapacitor Electrode ◽  
X Ray ◽  
Storage Mechanism ◽  
Transition Metal Sulfide ◽  
X Ray Absorption

In situ extended X-ray absorption fine structure analysis at the Mn K-edge and Co K-edge of MnCo2S4 nanowire as a supercapacitor electrode.

scholarly journals Unveiling Pseudocapacitive Charge Storage Behavior in FeWO4 Electrode Material by Operando X-ray Absorption Spectroscopy

2019 ◽  
Author(s):  
Nicolas Goubard-Bretesché ◽  
Olivier Crosnier ◽  
Camille Douard ◽  
Antonella Iadecola ◽  
Richard Retoux ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Electrode Material ◽  
Electrode Materials ◽  
Full Description ◽  
Charge Storage ◽  
X Ray ◽  
Storage Mechanism ◽  
Storage Behavior ◽  
Charge Storage Mechanism ◽  
X Ray Absorption

In nano-sized FeWO<sub>4</sub> electrode material, both Fe and W metal cations are suspected to be involved in the fast and reversible Faradaic surface reactions giving rise to its pseudocapacitive signature. As for any other pseudocapacitive materials, to fully understand the charge storage mechanism, a deeper insight into the involvement of the electroactive cations still has to be provided. The present paper illustrates how operando X-ray absorption spectroscopy (XAS) has been successfully used to collect data of unprecedented quality allowing to elucidate the complex electrochemical behavior of this multicationic pseudocapacitive material. Moreover, these in-depth experiments were obtained in real time upon cycling the electrode, which allowed investigating the reactions occurring in the material within a realistic timescale, which is compatible with electrochemical capacitors practical operation. Both Fe K-edge and W L<sub>3</sub>-edge measurements point out the involvement of the Fe<sup>3+</sup>/Fe<sup>2+</sup> redox couple in the charge storage while W<sup>6+</sup> acts as a spectator cation. The result of this study enables to unambiguously discriminate between the Faradaic and capacitive behavior of FeWO4. Beside these valuable insights toward the full description of the charge storage mechanism in FeWO<sub>4</sub>, this paper demonstrates the potential of operando X-ray absorption spectroscopy to enable a better material engineering for new high capacitance pseudocapacitive electrode materials.

scholarly journals Unveiling Pseudocapacitive Charge Storage Behavior in FeWO4 Electrode Material by Operando X-ray Absorption Spectroscopy

2019 ◽  
Author(s):  
Nicolas Goubard-Bretesché ◽  
Olivier Crosnier ◽  
Camille Douard ◽  
Antonella Iadecola ◽  
Richard Retoux ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Electrode Material ◽  
Electrode Materials ◽  
Full Description ◽  
Charge Storage ◽  
X Ray ◽  
Storage Mechanism ◽  
Storage Behavior ◽  
Charge Storage Mechanism ◽  
X Ray Absorption

In nano-sized FeWO<sub>4</sub> electrode material, both Fe and W metal cations are suspected to be involved in the fast and reversible Faradaic surface reactions giving rise to its pseudocapacitive signature. As for any other pseudocapacitive materials, to fully understand the charge storage mechanism, a deeper insight into the involvement of the electroactive cations still has to be provided. The present paper illustrates how operando X-ray absorption spectroscopy (XAS) has been successfully used to collect data of unprecedented quality allowing to elucidate the complex electrochemical behavior of this multicationic pseudocapacitive material. Moreover, these in-depth experiments were obtained in real time upon cycling the electrode, which allowed investigating the reactions occurring in the material within a realistic timescale, which is compatible with electrochemical capacitors practical operation. Both Fe K-edge and W L<sub>3</sub>-edge measurements point out the involvement of the Fe<sup>3+</sup>/Fe<sup>2+</sup> redox couple in the charge storage while W<sup>6+</sup> acts as a spectator cation. The result of this study enables to unambiguously discriminate between the Faradaic and capacitive behavior of FeWO4. Beside these valuable insights toward the full description of the charge storage mechanism in FeWO<sub>4</sub>, this paper demonstrates the potential of operando X-ray absorption spectroscopy to enable a better material engineering for new high capacitance pseudocapacitive electrode materials.

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

Insights into charge storage and electroactivation of mixed metal sulfides in alkaline media: NiCoMn ternary metal sulfide nano-needles forming core–shell structures for hybrid energy storage

2019 ◽  
Vol 7 (35) ◽  
pp. 20414-20424 ◽  
Author(s):  
Jaime S. Sanchez ◽  
Afshin Pendashteh ◽  
Jesus Palma ◽  
Marc Anderson ◽  
Rebeca Marcilla
Keyword(s):  
Energy Storage ◽  
Metal Sulfide ◽  
Shell Structures ◽  
Alkaline Media ◽  
Ex Situ ◽  
Metal Sulfides ◽  
Hybrid Energy ◽  
Storage Mechanism ◽  
Hybrid Energy Storage ◽  
Ternary Metal

NiCoMnS2 were subjected to ex situ/operando measurements, shedding light on energy storage mechanism and electroactivation of mixed sulfides in alkaline media.

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

scholarly journals Understanding the charge storage mechanism of conductive polymers as hybrid battery-capacitor materials in ionic liquids by in situ atomic force microscopy and electrochemical quartz crystal microbalance studies

2018 ◽  
Vol 6 (36) ◽  
pp. 17787-17799 ◽  
Author(s):  
Theresa Schoetz ◽  
Mario Kurniawan ◽  
Michael Stich ◽  
Ralf Peipmann ◽  
Igor Efimov ◽  
...  
Keyword(s):  
Quartz Crystal ◽  
Morphological Changes ◽  
Conductive Polymer ◽  
Electrochemical Quartz Crystal Microbalance ◽  
Charge Storage ◽  
Storage Mechanism ◽  
Force Microscopy ◽  
Atomic Force ◽  
Charge Storage Mechanism

Morphological changes of a conductive polymer in an ionic liquid during charging and discharging.

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