Triazole-amide isosteric pyridine-based supramolecular gelators in metal ion and biothiol sensing with excellent performance in adsorption of heavy metal ions and picric acid from water

2019 ◽  
Vol 43 (2) ◽  
pp. 934-945 ◽  
Author(s):  
Atanu Panja ◽  
Kumaresh Ghosh
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Marked Effect ◽  
Picric Acid ◽  
Excellent Performance ◽  
Ion Sensing ◽  
Gelling Properties ◽  
Metal Ion Sensing

Pyridine-based gelators 1–4 of triazole-amide isosteric relationship have been considered in metal ion sensing, heavy metal and picric acid adsorption from water. The change from triazole to isosteric amide has marked effect on gelling properties of the gelators.

Mechanistic insights into heavy metal ion sensing by NOS2-macrocyclic fluorosensors via the structure-function relationship: influences of fluorophores, solvents and anions

The Analyst ◽  
2020 ◽  
Vol 145 (5) ◽  
pp. 1667-1676 ◽  
Author(s):  
Eunji Lee ◽  
Huiyeong Ju ◽  
In-Hyeok Park ◽  
Sunhong Park ◽  
Mari Ikeda ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Structure Function ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Solvent Interactions ◽  
Ion Sensing ◽  
Metal Ion Sensing ◽  
Function Relationship ◽  
Heavy Metal Ion Sensing

The sensing properties of heavy metal ions by macrocycle-based fluorosensors are sensitive not only to cation–receptors and cation–fluorophore interactions but also to cation–anion (endo/exo-coordination modes) and/or cation–solvent interactions.

scholarly journals Ag-Functionalized Si Nanowire Arrays Aligned Vertically for SERS Detection of Captured Heavy Metal Ions by BSA

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 685
Author(s):  
Ai-Huei Chiou ◽  
Jun-Luo Wei ◽  
Ssu-Han Chen
Keyword(s):  
Heavy Metal ◽  
Raman Scattering ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Great Promise ◽  
Ag Nps ◽  
Water Contact ◽  
Oh Groups ◽  
Si Nanowire

A novel surface-enhanced Raman scattering (SERS)-based probe to capture heavy metal ion (Zn2+) by bovine serum albumin (BSA) using Si-nanowire (SiNW) arrays with silver nanoparticles (AgNPs) was developed. A layer with AgNPs was deposited on the SiNW surface by RF magnetron sputtering for enhancement of SERS signals. Using a high-resolution transmission electron microscope (HRTEM), the observation reveals that the AgNP layer with depths of 30–75 nm was successfully deposited on SiNW arrays. The Ag peaks in EDS and XRD spectra of SiNW arrays confirmed the presence of Ag particles on SiNW arrays. The WCA observations showed a high affinity of the Ag–SiNW arrays immobilized with BSA (water contact angle (WCA) = 87.1°) and ZnSO4 (WCA = 8.8°). The results of FTIR analysis illustrate that the conjugate bonds exist between zinc sulfate (ZnSO4) and –OH groups/–NH groups of BSA. The resulting SiNWs/Ag NPs composite interfaces showed large Raman scattering enhancement for the capture of heavy metal ions by BSA with a detection of 0.1 μM. BSA and ZnSO4 conjugations, illustrating specific SERS spectra with high sensitivity, which suggests great promise in developing label-free biosensors.

Modulation of Electronic Properties of Single Wall Carbon Nanotubes by the Presence of an Ionic Shell

2006 ◽  
Vol 915 ◽  
Author(s):  
Vladimir Dobrokhotov ◽  
Chris Berven
Keyword(s):  
Carbon Nanotubes ◽  
Heavy Metal ◽  
Band Structure ◽  
Metal Ion ◽  
Single Wall Carbon Nanotubes ◽  
Functionalized Carbon Nanotubes ◽  
Ion Sensing ◽  
Fixed Distance ◽  
Metal Ion Sensing ◽  
Heavy Metal Ion Sensing

AbstractWe report the change to the band structure of two types of carbon nanotubes due to the presence of an isolated, non-conducting, uniformly charged shell held at a fixed distance above their surfaces. We find that, depending on the chirality of the nanotube, the strain on the lattice causes the dispersion relationships to change. This change can result in a modification of the band structure which can induce a metal-semiconductor transition. We consider these effects as a possible mechanism for heavy-metal ion sensing by functionalized carbon-nanotubes.

Green synthesis of gold nanoparticles and its application for the trace level determination of painter's colic

RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 16284-16291 ◽  
Author(s):  
Chelladurai Karuppiah ◽  
Selvakumar Palanisamy ◽  
Shen-Ming Chen ◽  
R. Emmanuel ◽  
K. Muthupandi ◽  
...  
Keyword(s):  
Analytical Chemistry ◽  
Heavy Metal ◽  
Green Synthesis ◽  
Metal Ion ◽  
Trace Level ◽  
Ion Sensing ◽  
Metal Ion Sensing ◽  
Heavy Metal Ion Sensing ◽  
Trace Level Determination

The green synthesis of metal nanoparticles is found to be more attractive in various disciplines, including in analytical chemistry for heavy metal ion sensing.

scholarly journals Nanocelllulose Based Adsorbents for Heavy Metal Ions Removal

2021 ◽  
Author(s):  
Rongrong Si ◽  
Daiqi Wang ◽  
Yehong Chen ◽  
Dongmei Yu ◽  
Qijun Ding ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
High Performance ◽  
Advanced Technologies ◽  
Good Biocompatibility ◽  
Heavy Metal Ions Removal ◽  
Metal Ions Removal

Abstract Heavy metal ion pollutions are of serious threat for our human health, and advanced technologies on removal of heavy metal ions in water or soil are in the focus of intensive research worldwide. Nanocellulose based adsorbents are emerging as an environmentally friendly appealing materials platform for heavy metal ions removal as nanocellulose has higher specific surface area, excellent mechanical properties and good biocompatibility. In this review, we briefly compare the differences of three kinds of nanocellulose and their preparation method. Then we cover the most recent work on nanocellulose based adsorbents for heavy metal ions removal, and present an in-depth discussion of the modification technologies for nanocellulose in assembling high performance heavy ions adsorbent process. By introducing functional groups, such as amino, carboxyl, phenolic hydroxyl, and thiol, the nanocellulose based adsorbents not only remove single heavy metal ions through ion exchange, chelation/complexation/coordination, electrostatic attraction, hydrophobic actions, binding affinity and redox reactions, but also can selectively adsorb multiple heavy ions in water. Finally, some challenges of nanocellulose based adsorbents for heavy metal ions are also prospected. We anticipate that the review supplies some guides for nanocellulose based adsorbents applied in heavy metal ions removal field.

Functional group effect of isoreticular metal–organic frameworks on heavy metal ion adsorption

2018 ◽  
Vol 42 (11) ◽  
pp. 8864-8873 ◽  
Author(s):  
Leili Esrafili ◽  
Vahid Safarifard ◽  
Elham Tahmasebi ◽  
M. D. Esrafili ◽  
Ali Morsali
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Functional Group ◽  
Metal Organic Frameworks ◽  
Ion Adsorption ◽  
Group Effect ◽  
Metal Ion Adsorption ◽  
Metal Organic

We examined adsorption behavior of some MOFs having different functional groups in their pillar structures for adsorption of some heavy metal ions.

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