scholarly journals Influence of structure–activity relationships on through-space intervalence charge transfer in metal–organic frameworks with cofacial redox-active units

2019 ◽  
Vol 10 (5) ◽  
pp. 1392-1400 ◽  
Author(s):  
Bowen Ding ◽  
Carol Hua ◽  
Cameron J. Kepert ◽  
Deanna M. D'Alessandro
Keyword(s):  
Charge Transfer ◽  
Metal Organic Frameworks ◽  
Redox Active Ligands ◽  
Structure Activity Relationships ◽  
Structure Activity ◽  
Redox Active ◽  
Intervalence Charge Transfer ◽  
Metal Organic

Metal–organic frameworks incorporating cofacially-aligned redox-active ligands exhibit through-space intervalence charge transfer phenomena.

scholarly journals Quantification of the mixed-valence and intervalence charge transfer properties of a cofacial metal–organic framework via single crystal electronic absorption spectroscopy

2020 ◽  
Vol 11 (20) ◽  
pp. 5213-5220
Author(s):  
Patrick W. Doheny ◽  
Jack K. Clegg ◽  
Floriana Tuna ◽  
David Collison ◽  
Cameron J. Kepert ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Mixed Valence ◽  
Three Dimensional ◽  
Fundamental Understanding ◽  
Intervalence Charge Transfer ◽  
Metal Organic ◽  
Transfer Properties ◽  
Transfer Mechanisms

Gaining a fundamental understanding of charge transfer mechanisms in three-dimensional Metal–Organic Frameworks (MOFs) is crucial to the development of electroactive and conductive porous materials.

Through-Space Intervalence Charge Transfer as a Mechanism for Charge Delocalization in Metal–Organic Frameworks

2018 ◽  
Vol 140 (21) ◽  
pp. 6622-6630 ◽  
Author(s):  
Carol Hua ◽  
Patrick W. Doheny ◽  
Bowen Ding ◽  
Bun Chan ◽  
Michelle Yu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Metal Organic Frameworks ◽  
Charge Delocalization ◽  
Intervalence Charge Transfer ◽  
Metal Organic

Inter-ligands charge-transfer interactions in a photochromic and redox active zinc-organic framework

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yan Zhou ◽  
Lei Han ◽  
Wen-Jie Chen
Keyword(s):  
Charge Transfer ◽  
Metal Organic Frameworks ◽  
Transfer Mechanism ◽  
Conductive Materials ◽  
Charge Transfer Mechanism ◽  
Redox Active ◽  
Metal Organic ◽  
Organic Framework

Understanding the charge-transfer mechanism in metal-organic frameworks is of great importance to design photoactive, electroactive and conductive materials. A novel Zn (II)-organic framework shows 1D stair-like structure with strong -...

scholarly journals Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal–organic frameworks

2021 ◽  
Author(s):  
Shiyu Zhang ◽  
Dillip K. Panda ◽  
Ashok Yadav ◽  
Wei Zhou ◽  
Sourav Saha
Keyword(s):  
Electrical Conductivity ◽  
Charge Transfer ◽  
Space Charge ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Charge Movement ◽  
Charge Transfer Interaction ◽  
Intervalence Charge Transfer ◽  
Metal Organic

Through-space charge movement enabled by intervalence charge transfer interactions between π-stacked mixed-valent tetrathiafulvalene ligands creates electrical conductivity in three-dimensional metal–organic frameworks.

Bimetallic Fe/In metal-organic frameworks boosting charge transfer for enhancing pollutant degradation in wastewater

2020 ◽  
Vol 528 ◽  
pp. 147053 ◽  
Author(s):  
Siqi Wang ◽  
Fanqi Meng ◽  
Xuejiao Sun ◽  
Mingjun Bao ◽  
Jiawen Ren ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Metal Organic Frameworks ◽  
Pollutant Degradation ◽  
Metal Organic

Metal–Organic Frameworks Derived from Calcium and Strontium Complexes of a Redox-Active Ligand

2021 ◽  
Vol 60 (5) ◽  
pp. 3238-3248
Author(s):  
Natalia L. Bazyakina ◽  
Valentin M. Makarov ◽  
Sergey Yu. Ketkov ◽  
Artem S. Bogomyakov ◽  
Roman V. Rumyantcev ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Metal Organic

scholarly journals Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

2018 ◽  
Vol 20 (40) ◽  
pp. 25772-25779 ◽  
Author(s):  
Pavel M. Usov ◽  
Chanel F. Leong ◽  
Bun Chan ◽  
Mikihiro Hayashi ◽  
Hiroshi Kitagawa ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Pressure Dependence ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Transfer Characteristics ◽  
Donor Acceptor ◽  
Metal Organic ◽  
Transfer Properties ◽  
Organic Framework

Donor–Acceptor Metal–Organic Frameworks display redox and pressure dependent charge transfer properties.

scholarly journals Reaction of porphyrin-based surface-anchored metal–organic frameworks caused by prolonged illumination

2018 ◽  
Vol 20 (46) ◽  
pp. 29142-29151 ◽  
Author(s):  
Michael Adams ◽  
Nicolò Baroni ◽  
Michael Oldenburg ◽  
Felix Kraffert ◽  
Jan Behrends ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Metal Organic Frameworks ◽  
Triplet Exciton ◽  
Exciton Lifetime ◽  
Metal Organic

Upon prolonged illumination photoproducts are created in porphyrin-based metal–organic frameworks that limit the triplet exciton lifetime by charge-transfer quenching.

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