Enhancing light harvesting and charge separation of Cu2O photocathodes with spatially separated noble-metal cocatalysts towards highly efficient water splitting

2018 ◽  
Vol 6 (41) ◽  
pp. 20393-20401 ◽  
Author(s):  
Dong Chen ◽  
Zhifeng Liu ◽  
Zhengang Guo ◽  
Weiguo Yan ◽  
Ying Xin

A feasible strategy of spatially separated noble-metal cocatalysts for Cu2O photocathodes to enhance light harvesting and charge separation.

2018 ◽  
Vol 8 (15) ◽  
pp. 3883-3893 ◽  
Author(s):  
Yajun Zou ◽  
Jian-Wen Shi ◽  
Dandan Ma ◽  
Zhaoyang Fan ◽  
Chi He ◽  
...  

Cu2MoS4 was employed as a promising non-noble metal co-catalyst to couple with g-C3N4 for highly efficient water splitting.


2016 ◽  
Vol 9 (7) ◽  
pp. 2463-2469 ◽  
Author(s):  
Linchao Mu ◽  
Yue Zhao ◽  
Ailong Li ◽  
Shengyang Wang ◽  
Zhiliang Wang ◽  
...  

Spatial charge separation achieved on the anisotropic facets of high symmetry SrTiO3nanocrystals for highly efficient photocatalytic overall water splitting.


2016 ◽  
Vol 9 (8) ◽  
pp. 2633-2643 ◽  
Author(s):  
Fanyu Ning ◽  
Mingfei Shao ◽  
Simin Xu ◽  
Yi Fu ◽  
Ruikang Zhang ◽  
...  

TiO2/graphene/NiFe-layered double hydroxide nanorod arrays were fabricated as highly efficient photoanodes for photoelectrochemical water splitting with simultaneously enhanced charge separation and water oxidation efficiency.


CrystEngComm ◽  
2020 ◽  
Vol 22 (16) ◽  
pp. 2743-2755 ◽  
Author(s):  
Bowen Sun ◽  
Hui Wang ◽  
Jiakun Wu ◽  
Yanling Geng ◽  
Jixiang Xu ◽  
...  

Unique ZnS@[email protected] hollow nanospheres with abundant active sites and enhanced light-harvesting and charge separation demonstrate efficient H2 evolution from visible-light-driven water-splitting.


Author(s):  
Yelyn Sim ◽  
Jude John ◽  
Subramani Surendran ◽  
Byeolee Moon ◽  
Uk Sim

Photoelectrochemical water splitting is a promising field for sustainable energy production using hydrogen. Development of efficient catalysts is essential for resourceful hydrogen production. The most efficient catalysts reported to date have been extremely precious rare-earth metals. One of the biggest hurdles in this research area is the difficulty of developing highly efficient catalysts comparable to the noble metal catalysts. Here, we report that non-noble metal dichalcogenide (Co3Se4) catalysts made using a facile one-pot electrodeposition method, showed highly efficient photoelectrochemical activity on a Si photocathode. To enhance light collection and enlarge its surface area even further, we implemented surface nano-structuring on the Si surface. The nano-structured Si photoelectrode has an effective area greater than that of planar silicon and a wider absorption spectrum. Consequently, this approach exhibits reduced overvoltage as well as increased photo-catalytic activity. Such results show the importance of controlling the optimized interface between the surface structure of the photoelectrode and the electrodeposited co-catalyst on it to improve catalytic activity. This should enable other electrochemical reactions in a variety of energy conversion systems.


Nanoscale ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 6037-6046 ◽  
Author(s):  
Bing-Xin Zhou ◽  
Shuang-Shuang Ding ◽  
Yan Wang ◽  
Xiao-Rui Wang ◽  
Wei-Qing Huang ◽  
...  

Ti–N covalently bridged 0D/0D QCN/a-TiO2/r-TiO2 T-II/T-II heterojunctions for enhanced photocatalytic water splitting.


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