In situ synthesis of quasi-needle-like bimetallic organic frameworks on highly porous graphene scaffolds for efficient electrocatalytic water oxidation

2020 ◽  
Vol 56 (21) ◽  
pp. 3135-3138 ◽  
Author(s):  
Behnam Nourmohammadi Khiarak ◽  
Mahdi Hasanzadeh ◽  
Majdoddin Mojaddami ◽  
Hossein Shahriyar Far ◽  
Abdolreza Simchi
Keyword(s):  
Water Oxidation ◽  
Electrocatalytic Activity ◽  
Three Dimensional ◽  
In Situ Synthesis ◽  
One Dimensional ◽  
Porous Graphene ◽  
Highly Porous

We present enhanced electrocatalytic activity of three-dimensional graphene scaffolds by decoration with one-dimensional CoxNi1−x MOF nanostructures (0 ≤ x ≤ 1).

Exploring Nature's plasticity with a flexible probing tool, and finding new ways for its electronic distribution

2002 ◽  
Vol 30 (2) ◽  
pp. 78-82 ◽  
Author(s):  
M. Beier ◽  
M. Baum ◽  
H. Rebscher ◽  
R. Mauritz ◽  
A. Wixmerten ◽  
...  
Keyword(s):  
Three Dimensional ◽  
In Situ Synthesis ◽  
Light Modulation ◽  
Genomic Assays ◽  
Electronic Distribution ◽  
Spatial Light Modulation ◽  
Microarray Fabrication ◽  
Set Up ◽  
Microarray Format

Concepts and results are described for the use of a single, but extremely flexible, probing tool to address a wide variety of genomic questions. This is achieved by transforming genomic questions into a software file that is used as the design scheme for potentially any genomic assay in a microarray format. Microarray fabrication takes place in three-dimensional microchannel reaction carriers by in situ synthesis based on spatial light modulation. This set-up allows for maximum flexibility in design and realization of genomic assays. Flexibility is achieved at the molecular, genomic and assay levels. We have applied this technology to expression profiling and genotyping experiments.

scholarly journals Hydraulic modeling of combined sewers overflow integrating the results of the SWMM and CFX models.

2021 ◽  
Vol 37 (1) ◽  
Author(s):  
D. Pulgarín ◽  
J. Plaza ◽  
J. Ruge ◽  
J. Rojas
Keyword(s):  
Three Dimensional ◽  
Hydraulic Modeling ◽  
Dimensional Model ◽  
Three Dimensional Model ◽  
One Dimensional ◽  
Ansys Cfx ◽  
Combined Sewer ◽  
The One ◽  
Swmm Model

This study proposes a methodology for the calibration of combined sewer overflow (CSO), incorporating the results of the three-dimensional ANSYS CFX model in the SWMM one-dimensional model. The procedure consists of constructing calibration curves in ANSYS CFX that relate the input flow to the CSO with the overflow, to then incorporate them into the SWMM model. The results obtained show that the behavior of the flow over the crest of the overflow weir varies in space and time. Therefore, the flow of entry to the CSO and the flow of excesses maintain a non-linear relationship, contrary to the results obtained in the one-dimensional model. However, the uncertainty associated with the idealization of flow methodologies in one dimension is reduced under the SWMM model with kinematic wave conditions and simulating CSO from curves obtained in ANSYS CFX. The result obtained facilitates the calibration of combined sewer networks for permanent or non-permanent flow conditions, by means of the construction of curves in a three-dimensional model, especially when the information collected in situ is limited.

In Situ Synthesis of One-Dimensional Nanocrystalline Iron Materials by Electrodeposition Under Magnetic Field

2012 ◽  
Vol 42 (9) ◽  
pp. 1211-1216
Author(s):  
Qiaoxin Zhang ◽  
Shaofeng Zhou ◽  
Jiaming Zhang ◽  
Liang Zhang ◽  
Lining Yang ◽  
...  
Keyword(s):  
Magnetic Field ◽  
In Situ Synthesis ◽  
One Dimensional ◽  
Nanocrystalline Iron

scholarly journals An aqueous preoxidation method for monolithic perovskite electrocatalysts with enhanced water oxidation performance

2016 ◽  
Vol 2 (10) ◽  
pp. e1600495 ◽  
Author(s):  
Bo-Quan Li ◽  
Cheng Tang ◽  
Hao-Fan Wang ◽  
Xiao-Lin Zhu ◽  
Qiang Zhang
Keyword(s):  
Water Oxidation ◽  
Fenton Reaction ◽  
Nickel Foam ◽  
Three Dimensional ◽  
Active Phase ◽  
Perovskite Oxides ◽  
High Temperature Annealing ◽  
Current Collectors ◽  
Oxidation Performance

Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot survive. We propose a preoxidization coupled electrodeposition strategy in which Co2+ is preoxidized to Co3+ through cobalt Fenton reaction in aqueous solution, whereas the reductive nickel framework is well maintained during the sequential annealing under nonoxidative atmosphere. The in situ–generated Co3+ is inherited into oxidized perovskites deposited on 3D nickel foam, rendering the monolithic perovskite electrocatalysts with extraordinary OER performance with an ultralow overpotential of 350 mV required for 10 mA cm−2, a very small Tafel slope of 59 mV dec−1, and superb stability in 0.10 M KOH. Therefore, we inaugurate a unique strategy for in situ hybridization of oxidative active phase with reductive framework, affording superb reactivity of perovskite electrocatalyst for efficient water oxidation.

Sign in / Sign up

Export Citation Format

Share Document