Unique reactivity of B in B[Ge9Y3]3 (Y = H, CH3, BO, CN): formation of a Lewis base
Keyword(s):
Boron compounds usually exhibit Lewis acidity at the boron center due to the presence of vacant p-orbitals. But using Zintl-ion based groups (Ge9Y3, Y = H, CH3, BO, CN), we can alter Lewis acid nature of B to a Lewis base.
2005 ◽
Vol 83
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pp. 2098-2105
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2013 ◽
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pp. 289-294
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pp. 1350076
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pp. 538
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pp. 956-961
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