The impact of an isoreticular expansion strategy on the performance of iodine catalysts supported in multivariate zirconium and aluminum metal–organic frameworks

2019 ◽  
Vol 48 (19) ◽  
pp. 6445-6454 ◽  
Author(s):  
Babak Tahmouresilerd ◽  
Michael Moody ◽  
Louis Agogo ◽  
Anthony F. Cozzolino
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Expansion Strategy ◽  
Aluminum Metal ◽  
Metal Organic ◽  
The Impact

A new iodine catalyst was supported in two different MOFs and the catalytic activity for the oxidation of hydroquinones and catechols was evaluated.

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Improving porosity and water uptake of aluminum metal-organic frameworks (Al-MOFs) as graphite oxide (GO) composites

2021 ◽  
pp. 111352
Author(s):  
Ülkü Kökçam-Demir ◽  
Niels Tannert ◽  
Marco Bengsch ◽  
Alex Spieß ◽  
Carsten Schlüsener ◽  
...  
Keyword(s):  
Water Uptake ◽  
Graphite Oxide ◽  
Metal Organic Frameworks ◽  
Aluminum Metal ◽  
Metal Organic

Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks

2016 ◽  
Vol 55 (15) ◽  
pp. 7425-7431 ◽  
Author(s):  
Selda Halis ◽  
A. Ken Inge ◽  
Niklas Dehning ◽  
Thomas Weyrich ◽  
Helge Reinsch ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Aluminum ◽  
Aluminum Metal ◽  
Metal Organic

Controllable synthesis of urchin-like hierarchical superstructure MOFs with high catalytic activity and stability

2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Controllable Synthesis ◽  
Metal Organic ◽  
Self Assembled

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...

Enzyme encapsulation in metal–organic frameworks for applications in catalysis

CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4082-4091 ◽  
Author(s):  
Marek B. Majewski ◽  
Ashlee J. Howarth ◽  
Peng Li ◽  
Michael R. Wasielewski ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Enzyme Encapsulation ◽  
Metal Organic

Various methods for encapsulating enzymes in metal–organic frameworks are discussed and the catalytic activity of biocomposites prepared using these methods is highlighted.

The impact of metal ions on photoinduced electron-transfer properties: four photochromic metal–organic frameworks based on a naphthalenediimide chromophore

CrystEngComm ◽  
2018 ◽  
Vol 20 (17) ◽  
pp. 2430-2439 ◽  
Author(s):  
Hui-Ling Xu ◽  
Xiao-Shan Zeng ◽  
Jie Li ◽  
Yu-Ci Xu ◽  
Hai-Jiang Qiu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Ions ◽  
Significant Role ◽  
Photoinduced Electron Transfer ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Electron Transfer Properties ◽  
The Impact ◽  
Transfer Properties

Four photochromic MOFs show that electron-withdrawing capabilities of metal ions play a significant role in tuning the photosensitivity of photochromic MOFs.

Sign in / Sign up

Export Citation Format

Share Document