Effect of bulky substituents in the donor and acceptor terminal groups on solvatochromism of Brooker's merocyanine

2019 ◽  
Vol 43 (19) ◽  
pp. 7379-7385 ◽  
Author(s):  
Andrii V. Kulinich ◽  
Vladimir V. Kurdyukov ◽  
Alexander A. Ishchenko
Keyword(s):  
Spectral Properties ◽  
Donor And Acceptor ◽  
Nucleophilic Solvation ◽  
Brooker’S Merocyanine

Comparison of spectral properties of stilbazolium dyes in various solvents has exposed the influence of electrophilic and nucleophilic solvation on their solvatochromism.

Variation of Donor and Acceptor Strength in Analogues of Brooker’s Merocyanine and Generalization to Various Classes of Charge Transfer Compounds

2019 ◽  
Vol 123 (13) ◽  
pp. 2694-2708 ◽  
Author(s):  
M. Dekhtyar ◽  
W. Rettig ◽  
A. Rothe ◽  
V. Kurdyukov ◽  
A. Tolmachev
Keyword(s):  
Charge Transfer ◽  
Donor And Acceptor ◽  
Brooker’S Merocyanine

Model of multicomponent narrow-band periodical non-stationary random signal

2020 ◽  
Vol 2020 (48) ◽  
pp. 17-24
Author(s):  
I.M. Javorskyj ◽  
◽  
R.M. Yuzefovych ◽  
P.R. Kurapov ◽  
◽  
...  
Keyword(s):  
Time Series ◽  
Real Time ◽  
Hilbert Transform ◽  
Spectral Properties ◽  
Narrow Band ◽  
Analytic Signal ◽  
Random Signal ◽  
Hilbert Transformation ◽  
The Hilbert Transform

The correlation and spectral properties of a multicomponent narrowband periodical non-stationary random signal (PNRS) and its Hilbert transformation are considered. It is shown that multicomponent narrowband PNRS differ from the monocomponent signal. This difference is caused by correlation of the quadratures for the different carrier harmonics. Such features of the analytic signal must be taken into account when we use the Hilbert transform for the analysis of real time series.

Structure and Spectral Properties of New Composites Based on Metal Alkanoates with Gold Nanoparticles

2015 ◽  
Vol 60 (04) ◽  
pp. 356-361 ◽  
Author(s):  
A. Tolochko ◽  
◽  
P. Teselko ◽  
A. Lyashchova ◽  
D. Fedorenko ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Spectral Properties

Stoichiometric Determination of Graphite Intercalation Compounds Using Rutherford Backscatiering Spectrometry

1983 ◽  
Vol 27 ◽  
Author(s):  
L. Salamanca-Riba ◽  
B.S. Elman ◽  
M.S. Dresselhaus ◽  
T. Venkatesan
Keyword(s):  
Experimental Error ◽  
Rutherford Backscattering Spectrometry ◽  
Rutherford Backscattering ◽  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
X Ray ◽  
Donor And Acceptor ◽  
Graphite Intercalation ◽  
Non Destructive

ABSTRACTRutherford backscattering spectrometry (RBS) is used to characterize the stoichiometry of graphite intercalation compounds (GIC). Specific application is made to several stages of different donor and acceptor compounds and to commensurate and incommensurate intercalants. A deviation from the theoretical stoichiometry is measured for most of the compounds using this non-destructive method. Within experimental error, the RBS results agree with those obtained from analysis of the (00ℓ) x-ray diffractograms and weight uptake measurements on the same samples.

PHYSICOCHEMICAL POINTS OF SYNTHESIS OF LONG PERSISTENCE PHOSPHORS ON THE BASIS OF YTTRIUM OXOSULFIDE. REPORT 3. STUDY OF Er3+ IONS INFLUENCE ON SPECTRAL PROPERTIES OF Y2O2S: Ti, Mg

2007 ◽  
Vol 3 (2) ◽  
pp. 20-26
Author(s):  
A.A. Bogatureva ◽  
◽  
V.M. Ishenko ◽  
O.Y. Manashirov ◽  
A.N. Georgobiani ◽  
...  
Keyword(s):  
Spectral Properties

Investigation of Adsorption Effect of Carbon Monoxide on Coniine: A DFT Study

2021 ◽  
Vol 17 ◽  
Author(s):  
Siyamak Shahab ◽  
Masoome Sheikhi ◽  
Mehrnoosh Khaleghian ◽  
Marina Murashko ◽  
Mahin Ahmadianarog ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Gas Phase ◽  
Density Functional ◽  
Energy Gap ◽  
Adsorption Effect ◽  
Chemical Shift Tensors ◽  
Solvent Water ◽  
Donor And Acceptor ◽  
Before And After ◽  
Electron Donor And Acceptor

: For the first time in the present study, the non-bonded interaction of the Coniine (C8H17N) with carbon monoxide (CO) was investigated by density functional theory (DFT/M062X/6-311+G*) in the gas phase and solvent water. The adsorption of the CO over C8H17N was affected on the electronic properties such as EHOMO, ELUMO, the energy gap between LUMO and HOMO, global hardness. Furthermore, chemical shift tensors and natural charge of the C8H17N and complex C8H17N/CO were determined and discussed. According to the natural bond orbital (NBO) results, the molecule C8H17N and CO play as both electron donor and acceptor at the complex C8H17N/CO in the gas phase and solvent water. On the other hand, the charge transfer is occurred between the bonding, antibonding or nonbonding orbitals in two molecules C8H17N and CO. We have also investigated the charge distribution for the complex C8H17N/CO by molecular electrostatic potential (MEP) calculations using the M062X/6-311+G* level of theory. The electronic spectra of the C8H17N and complex C8H17N/CO were calculated by time dependent DFT (TD-DFT) for investigation of the maximum wavelength value of the C8H17N before and after the non-bonded interaction with the CO in the gas phase and solvent water. Therefore, C8H17N can be used as strong absorbers for air purification and reduce environmental pollution.

Sign in / Sign up

Export Citation Format

Share Document