Rational design of thermally activated delayed fluorescence emitters with aggregation-induced emission employing combined charge transfer pathways for fabricating efficient non-doped OLEDs

2019 ◽  
Vol 7 (30) ◽  
pp. 9413-9422 ◽  
Author(s):  
Fulong Ma ◽  
Yu Cheng ◽  
Yu Zheng ◽  
Hefang Ji ◽  
Kamran Hasrat ◽  
...  

Achieving combined charge transfer pathways in novel thermally activated delayed fluorescence emitters with aggregation-induced emission features.

2019 ◽  
Vol 10 (10) ◽  
pp. 2915-2923 ◽  
Author(s):  
Xingdong Wang ◽  
Shumeng Wang ◽  
Jianhong Lv ◽  
Shiyang Shao ◽  
Lixiang Wang ◽  
...  

Through-space charge transfer hexaarylbenzene dendrimers containing circularly-arrayed electron donors and acceptors exhibit thermally activated delayed fluorescence and aggregation-induced emission effects, giving EQE of 14.2% for solution-processed OLEDs.


CrystEngComm ◽  
2021 ◽  
Author(s):  
yuanyuan xu ◽  
X.G. Gao ◽  
Jiancai Leng ◽  
Jianzhong Fan

Apart from the thermally activated delayed fluorescence (TADF) systems, new-generation fluorescent materials with aggregation induced emission (AIE) and hybridized local and charge transfer (HLCT) state features have shown promising applications...


2017 ◽  
Vol 139 (13) ◽  
pp. 4894-4900 ◽  
Author(s):  
Hiroyuki Tsujimoto ◽  
Dong-Gwang Ha ◽  
Georgios Markopoulos ◽  
Hyun Sik Chae ◽  
Marc A. Baldo ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1125
Author(s):  
Teng Teng ◽  
Jinfan Xiong ◽  
Gang Cheng ◽  
Changjiang Zhou ◽  
Xialei Lv ◽  
...  

A new series of tetrahedral heteroleptic copper(I) complexes exhibiting efficient thermally-activated delayed fluorescence (TADF) in green to orange electromagnetic spectral regions has been developed by using D-A type N^N ligand and P^P ligands. Their structures, electrochemical, photophysical, and electroluminescence properties have been characterized. The complexes exhibit high photoluminescence quantum yields (PLQYs) of up to 0.71 at room temperature in doped film and the lifetimes are in a wide range of 4.3–24.1 μs. Density functional theory (DFT) calculations on the complexes reveal the lowest-lying intraligand charge-transfer excited states that are localized on the N^N ligands. Solution-processed organic light emitting diodes (OLEDs) based on one of the new emitters show a maximum external quantum efficiency (EQE) of 7.96%.


Author(s):  
Kai Zhang ◽  
Jianzhong Fan ◽  
Chuankui Wang ◽  
Lili Lin

Modulating the relationship between molecular structures and luminescent properties as well as the charge transfer property for deep-red thermally activated delayed fluorescence (TADF) emitters has always been a powerful challenge,...


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