Dynamic metal–organic frameworks for the separation of hydrogen isotopes

2020 ◽  
Vol 49 (46) ◽  
pp. 16617-16622
Author(s):  
Zhanfeng Ju ◽  
El-Sayed M. El-Sayed ◽  
Daqiang Yuan
Keyword(s):  
Structural Transformation ◽  
Hydrogen Isotope ◽  
Isotope Separation ◽  
Metal Organic Frameworks ◽  
Hydrogen Isotopes ◽  
Gate Opening ◽  
Metal Organic ◽  
Reversible Structural Transformation ◽  
Or Gate

Reversible structural transformation along with breathing effect or gate-opening phenomena in some dynamic MOFs provide opportunity to operate or to enhance kinetic quantum sieving (KQS) for hydrogen isotope separation.

Exploiting Diffusion Barrier and Chemical Affinity of Metal–Organic Frameworks for Efficient Hydrogen Isotope Separation

2017 ◽  
Vol 139 (42) ◽  
pp. 15135-15141 ◽  
Author(s):  
Jin Yeong Kim ◽  
Rafael Balderas-Xicohténcatl ◽  
Linda Zhang ◽  
Sung Gu Kang ◽  
Michael Hirscher ◽  
...  
Keyword(s):  
Diffusion Barrier ◽  
Hydrogen Isotope ◽  
Isotope Separation ◽  
Metal Organic Frameworks ◽  
Chemical Affinity ◽  
Metal Organic

Screening of Metal–Organic Frameworks for Highly Effective Hydrogen Isotope Separation by Quantum Sieving

2018 ◽  
Vol 10 (38) ◽  
pp. 32128-32132 ◽  
Author(s):  
Guopeng Han ◽  
Yu Gong ◽  
Hongliang Huang ◽  
Dawei Cao ◽  
Xiaojun Chen ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Separation ◽  
Metal Organic Frameworks ◽  
Highly Effective ◽  
Metal Organic ◽  
Effective Hydrogen

Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal–organic frameworks

2018 ◽  
Vol 54 (72) ◽  
pp. 10183-10186 ◽  
Author(s):  
Mengmeng Wang ◽  
Xixi Meng ◽  
Fen Song ◽  
Yanfei He ◽  
Wei Shi ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Single Molecule ◽  
Metal Organic Frameworks ◽  
Single Molecule Magnet ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Reversible Structural Transformation

The structural transformation between Ln-MOFs 1 and 2 and the corresponding switchable “on/off” single-molecule magnet behavior have been studied.

Hydrogen isotope separation in metal-organic frameworks: Kinetic or chemical affinity quantum-sieving?

2015 ◽  
Vol 216 ◽  
pp. 133-137 ◽  
Author(s):  
Ievgeniia Savchenko ◽  
Andreas Mavrandonakis ◽  
Thomas Heine ◽  
Hyunchul Oh ◽  
Julia Teufel ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Separation ◽  
Metal Organic Frameworks ◽  
Chemical Affinity ◽  
Metal Organic
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