Efficient chemosensors for toxic pollutants based on photoluminescent Zn(II) and Cd(II) metal-organic networks

2021 ◽  
Author(s):  
Luis David Rosales-Vazquez ◽  
Alejandro Dorazco-González ◽  
Victor Sanchez-Mendieta

Optical sensors with high sensitivity and selectivity, as important analytical tools for chemical and environmental research, can be accomplished by straightforward synthesis of luminescent one-, two- and three-dimensional Zn(II) and...

2017 ◽  
Vol 4 (2) ◽  
pp. 256-260 ◽  
Author(s):  
Mei-Hui Yu ◽  
Tong-Liang Hu ◽  
Xian-He Bu

A new three-dimensional (3D) metal–organic framework exhibits high sensitivity and selectivity for Al3+ ions as a “turn on” fluorescent sensor.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Yang Qiao ◽  
Zeqi Li ◽  
Mei-Hui Yu ◽  
Ze Chang ◽  
Xian-He Bu

High sensitivity and selectivity for detection of metal ions are very important to protect human health. Fluorescent metal-organic framework (MOF) as a new sensing material has attracted more and more...


2021 ◽  
Vol 17 ◽  
Author(s):  
Xiaomeng Zhou ◽  
Li Shang

: Adenosine 5'-triphosphate (ATP) plays a significant role in biological processes and the ATP level is closely associated with many diseases. In order to detect ATP in live cells, tissues and body fluids with a high sensitivity and selectivity, researchers have developed various sensing strategies. Particularly, owing to distinct physicochemical properties of nanomaterials and high sensitivity of fluorescence, a great deal of efforts have been devoted to developing nanomaterials-based approaches for fluorescent ATP sensing in recent years. In this review, we focus on the current development of nanomaterial-based fluorescent ATP sensors and discuss the sensing mechanisms in detail. The advantages and disadvantages of ATP sensing using different kinds of nanomaterials, including carbon nanomaterials, metal nanoparticles, semiconductor quantum dots, metal-organic frameworks and up-conversion nanoparticles have been thoroughly compared and discussed. Finally, current challenges and future prospects in this field are given.


2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Usman Ali

Metal organic networks (MONs) are defined as one, two and three dimensional unique complex structures of porous material and subclass of polymer’s coordination. These networks also show extreme surface area, morphology, excellent chemical stability, large pore volume, highly crystalline materials. The major advantages of MONs are tailorability, structural diversity, versatile applications, highly controllable nano-structures and functionality. So, the multi-functional applications of these MONs are made them more helpful tools in many fields of science in recent decade. In this paper, we light on the two different MONs with respect to the number of increasing layers of metal and organic ligands together. We define the novel multiplicative Zagreb connection indices (ZCIs) such that multiplicative fourth ZCI and multiplicative fifth ZCI. We also compute the main results for multiplicative Zagreb connection indices of two different MONs (zinc oxide and zinc silicate).


2015 ◽  
Vol 39 (10) ◽  
pp. 7858-7862 ◽  
Author(s):  
Xiao-Li Hu ◽  
Chao Qin ◽  
Xin-Long Wang ◽  
Kui-Zhan Shao ◽  
Zhong-Min Su

Employing a C3 symmetric ligand, one new cluster-based MOF [Cd2.5Na(NTB)2(DMF)4]·3DMF (1) has been successfully obtained. The results reveal that compound 1 could be applied as a fluorescence sensor for TNP with high sensitivity and selectivity.


MRS Advances ◽  
2019 ◽  
Vol 4 (5-6) ◽  
pp. 319-324
Author(s):  
Takuji Ube ◽  
Akizumi Kawamoto ◽  
Tomoya Nishi ◽  
Takashi Ishiguro

ABSTRACTNano-porous palladium (Pd) thin films could potentially be applied to hydrogen gas sensing materials with high sensitivity and selectivity. In our previous study, a nano-porous Pd film was fabricated with a three-dimensional network structure from an AlPd mother alloy film by a dealloying method using the chelating ability of an organic acid. This process was simple and environmentally friendly because it only required organic acid in a ppm concentration, and did not exhaust a strong acid waste solution, including heavy metal ions. This method was modified to improve the Pd purity of the dealloyed specimen, reaction rate, and morphology control. In this study, the existence of a composition undulation pattern was shown in the AlPd mother alloy film, and its effects on the morphology of the dealloyed specimen were evaluated. Furthermore, this pattern could be controlled by N2 gas addition to the Ar sputtering gas during the preparation of the AlPd mother alloy film.


2019 ◽  
Vol 48 (48) ◽  
pp. 17945-17952 ◽  
Author(s):  
Tian-Yu Liu ◽  
Xiang-Long Qu ◽  
Bing Yan

A novel luminescent probe based on a Eu3+ functionalized MOF hybrid (Eu3+@1) with high sensitivity and selectivity has been proved to possess enormous potential for the determination of fleroxacin in human serum and urine.


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