Two-step nonlinear optical switch in a hydrogen-bonded perovskite-type crystal

2022 ◽  
Author(s):  
Xiu-Ni Hua ◽  
Wan-Ying Zhang ◽  
Ping-Ping Shi

Switchable nonlinear optical (NLO) materials have aroused broad interest on account of their captivating optical and electronic properties. We demonstrate a novel perovskite-type crystal with exceptional hydrogen bond interactions that...

2014 ◽  
Vol 16 (34) ◽  
pp. 18418-18424 ◽  
Author(s):  
Ahmed M. Hafez ◽  
Noha M. Salem ◽  
Nageh K. Allam

Coupling DFT and FDTD reveals the optical and electronic properties of perovskite materials.


2007 ◽  
Author(s):  
Abdalla Darwish ◽  
Brent Koplitz ◽  
Nickolai Kukhtarev ◽  
Xiaodong Zhang ◽  
Robet Combs ◽  
...  

2016 ◽  
Vol 1125 ◽  
pp. 315-322 ◽  
Author(s):  
Ömer Tamer ◽  
Moazzam H. Bhatti ◽  
Uzma Yunus ◽  
Davut Avcı ◽  
Yusuf Atalay ◽  
...  

2003 ◽  
Author(s):  
Abdalla M. Darwish ◽  
Brent D. Koplitz ◽  
Nicholai V. Kukhtarev ◽  
Oliva Mitchell ◽  
R. Haydel ◽  
...  

Author(s):  
Mahadevappa Y. Kariduraganavar ◽  
Radha V. Doddamani ◽  
Balachandar Waddar ◽  
Saidi Reddy Parne

Nonlinear optical (NLO) materials have gained much attention during the last two decades owing to their potentiality in the field of optical data storage, optical information processing, optical switching, and telecommunication. NLO responsive macroscopic devices possess extensive applications in our day to day life. Such devices are considered as assemblies of several macroscopic components designed to achieve specific functions. The extension of this concept to the molecular level forms the basis of molecular devices. In this context, the design of NLO switches, that is, molecules characterized by their ability to alternate between two or more chemical forms displaying contrasts in one of their NLO properties, has motivated many experimental and theoretical works. Thus, this chapter focuses on the rational design of molecular NLO switches based on stimuli and materials with extensive examples reported in the literature. The factors affecting the efficiency of optical switches are discussed. The device fabrication of optical switches and their efficiency based on the optical switch, internal architecture, and substrate materials are described. In the end, applications of switches and future prospectus of designing new molecules with references are suitably discussed.


2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>


2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>


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