Two-step nonlinear optical switch in a hydrogen-bonded perovskite-type crystal

2022 ◽  
Author(s):  
Xiu-Ni Hua ◽  
Wan-Ying Zhang ◽  
Ping-Ping Shi
Keyword(s):  
Hydrogen Bond ◽  
Electronic Properties ◽  
Nonlinear Optical ◽  
Optical Switch ◽  
Hydrogen Bond Interactions ◽  
Optical And Electronic Properties ◽  
Nlo Materials ◽  
Perovskite Type ◽  
Broad Interest ◽  
Type Crystal

Switchable nonlinear optical (NLO) materials have aroused broad interest on account of their captivating optical and electronic properties. We demonstrate a novel perovskite-type crystal with exceptional hydrogen bond interactions that...

Nonlinear optical and electronic properties of SiC/PMMA/Ge/Fe waveguide for device applications

2007 ◽  
Author(s):  
Abdalla Darwish ◽  
Brent Koplitz ◽  
Nickolai Kukhtarev ◽  
Xiaodong Zhang ◽  
Robet Combs ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Nonlinear Optical ◽  
Optical And Electronic Properties ◽  
Device Applications

Unique nonlinear optical and electronic properties of SiC:Ge waveguide for device applications

2003 ◽  
Author(s):  
Abdalla M. Darwish ◽  
Brent D. Koplitz ◽  
Nicholai V. Kukhtarev ◽  
Oliva Mitchell ◽  
R. Haydel ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Nonlinear Optical ◽  
Optical And Electronic Properties ◽  
Device Applications

scholarly journals Nonlinear Optical Responsive Molecular Switches

2021 ◽  
Author(s):  
Mahadevappa Y. Kariduraganavar ◽  
Radha V. Doddamani ◽  
Balachandar Waddar ◽  
Saidi Reddy Parne
Keyword(s):  
Data Storage ◽  
Optical Switching ◽  
Rational Design ◽  
Nonlinear Optical ◽  
Optical Switch ◽  
Optical Switches ◽  
Device Fabrication ◽  
Optical Data ◽  
Factors Affecting ◽  
Nlo Materials

Nonlinear optical (NLO) materials have gained much attention during the last two decades owing to their potentiality in the field of optical data storage, optical information processing, optical switching, and telecommunication. NLO responsive macroscopic devices possess extensive applications in our day to day life. Such devices are considered as assemblies of several macroscopic components designed to achieve specific functions. The extension of this concept to the molecular level forms the basis of molecular devices. In this context, the design of NLO switches, that is, molecules characterized by their ability to alternate between two or more chemical forms displaying contrasts in one of their NLO properties, has motivated many experimental and theoretical works. Thus, this chapter focuses on the rational design of molecular NLO switches based on stimuli and materials with extensive examples reported in the literature. The factors affecting the efficiency of optical switches are discussed. The device fabrication of optical switches and their efficiency based on the optical switch, internal architecture, and substrate materials are described. In the end, applications of switches and future prospectus of designing new molecules with references are suitably discussed.

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

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