On the efficiency of perovskite solar cells with a back reflector: effect of a hole transport material

Author(s):  
F. Bonnín-Ripoll ◽  
Ya. B. Martynov ◽  
R. G. Nazmitdinov ◽  
G. Cardona ◽  
R. Pujol-Nadal

A thorough optical + electrical + Lambertian scattering analysis determines the optimal thickness of a perovskite thin-film solar cell revealing its high efficiency with inorganic HTMs.

2016 ◽  
Vol 9 (7) ◽  
pp. 2326-2333 ◽  
Author(s):  
Guan-Woo Kim ◽  
Gyeongho Kang ◽  
Jinseck Kim ◽  
Gang-Young Lee ◽  
Hong Il Kim ◽  
...  

A dopant–free polymeric hole transport material (HTM), RCP, based on benzo[1,2-b:4,5:b′]dithiophene and 2,1,3-benzothiadiazole exhibited a high efficiency of 17.3% in a perovskite solar cell and maintained its initial efficiency for over 1400 hours.


2013 ◽  
Vol 712-715 ◽  
pp. 309-312 ◽  
Author(s):  
Ming Kun Xu

P+a-SiC/ I nc-Si/N+a-Si structure solar cells is simulated by AMPS-1D program package to characterize the new thin film solar cell. In order to analyze the characteristics of the device, the thickness of layer are considered. The results show that the thickness of layer and the value of layer have a great effect on the conversion efficiency. Our results suggest a high performance P a-SiC/ I nc-Si/N a-Si structure solar cells with high efficiency of 14.411% and fill factor of 0.738. The simulation result is potentially valuable in exploring gradual bandgap P+a-SiC/I nc-Si/N+a-Si structure solar cells with high performance.


2015 ◽  
Vol 3 (28) ◽  
pp. 14902-14909 ◽  
Author(s):  
Ying Liu ◽  
Shulin Ji ◽  
Shuxin Li ◽  
Weiwei He ◽  
Ke Wang ◽  
...  

Perovskite solar cells have been widely investigated owing to their high efficiency and low production cost.


2017 ◽  
Vol 10 (5) ◽  
pp. 1134-1141 ◽  
Author(s):  
Bofei Liu ◽  
Lisha Bai ◽  
Tiantian Li ◽  
Changchun Wei ◽  
Baozhang Li ◽  
...  

A highly efficient quadruple-junction silicon based thin-film solar cell with a remarkably high open-circuit voltage was demonstrated to inspire functional photoelectrical devices for environmental applications.


2018 ◽  
Vol 11 (11) ◽  
pp. 3310-3320 ◽  
Author(s):  
Mohammad Mahdi Tavakoli ◽  
Wolfgang Tress ◽  
Jovana V. Milić ◽  
Dominik Kubicki ◽  
Lyndon Emsley ◽  
...  

Non-radiative recombination losses are reduced drastically by addition of adamantylammonium iodide (ADAHI) into the hole transporting layer (HTL) in a perovskite solar cell, resulting in high efficiency (∼22%), increased Voc up to 1245 mV, and enhanced electro-luminescence EQE to 2.5%.


2018 ◽  
Vol 11 (2) ◽  
pp. 394-406 ◽  
Author(s):  
Heping Shen ◽  
The Duong ◽  
Jun Peng ◽  
Daniel Jacobs ◽  
Nandi Wu ◽  
...  

A perovskite/CIGS tandem configuration is an attractive and viable approach to achieve an ultra-high efficiency and cost-effective all-thin-film solar cell.


The researchers now days are avid of solar cells despite the efficiency issues. As lead-based halide perovskite exhibit toxic nature alternatives for the anti- toxic perovskite solar cells(PSCs) are gaining much research. Bis(sulfanylidene )tungsten is a toxic free feasible emerging option with direct band gap of value 1.8 eV. Tungsten disulfide is other chemical name of Bis(sulfanylidene)tungsten. In this paper, perovskite solar cell (PSC) with Bis(sulfanylidene)tungsten (WS2 ) as electron transport layer and spiro-OMeTAD as hole transport layer is modelled and simulated using SCAPS software to analyze performance parameters. The device simulations results are compared for comprehensive defect study of WS2 as ETL. With integration of WS2 and spiro-OMeTAD in the perovskite design, the outcomes are proficient enough with 25.96% of PCE, 22.06 mA/cm2 Jsc, 1.280V Voc and 91.76% FF. Launching the batch setup for absorber layer thickness further resulted with competent PCE 27.78%. The outcomes signified that the toxic-free WS2 based PSC can be a prominent upcoming perspective in terms of environmentally pristine nature and capitulate comparative high efficiency


Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2321
Author(s):  
Yizhou He ◽  
Liyifei Xu ◽  
Cheng Yang ◽  
Xiaowei Guo ◽  
Shaorong Li

In the last decade, perovskite solar cells have made a quantum leap in performance with the efficiency increasing from 3.8% to 25%. However, commercial perovskite solar cells have faced a major impediment due to toxicity and stability issues. Therefore, lead-free inorganic perovskites have been investigated in order to find substitute perovskites which can provide a high efficiency similar to lead-based perovskites. In recent studies, as a kind of lead-free inorganic perovskite material, Cs4CuSb2Cl12 has been demonstrated to possess impressive photoelectric properties and excellent environmental stability. Moreover, Cs4CuSb2Cl12 nanocrystals have smaller effective photo-generated carrier masses than bulk Cs4CuSb2Cl12, which provides excellent carrier mobility. To date, there have been no reports about Cs4CuSb2Cl12 nanocrystals used for making solar cells. To explore the potential of Cs4CuSb2Cl12 nanocrystal solar cells, we propose a lead-free perovskite solar cell with the configuration of FTO/ETL/Cs4CuSb2Cl12 nanocrystals/HTL/Au using a solar cell capacitance simulator. Moreover, we numerically investigate the factors that affect the performance of the Cs4CuSb2Cl12 nanocrystal solar cell with the aim of enhancing its performance. By selecting the appropriate hole transport material, electron transport material, thickness of the absorber layer, doping densities, defect density in the absorber, interface defect densities, and working temperature point, we predict that the Cs4CuSb2Cl12 nanocrystal solar cell with the FTO/TiO2/Cs4CuSb2Cl12 nanocrystals/Cu2O/Au structure can attain a power conversion efficiency of 23.07% at 300 K. Our analysis indicates that Cs4CuSb2Cl12 nanocrystals have great potential as an absorbing layer towards highly efficient lead-free all-inorganic perovskite solar cells.


Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 886
Author(s):  
Shou-En Chiang ◽  
Qi-Bin Ke ◽  
Anjali Chandel ◽  
Hsin-Ming Cheng ◽  
Yung-Sheng Yen ◽  
...  

A high-efficiency inverted-type CH3NH3PbI3 (MAPbI3) solar cell was fabricated by using a ultrathin poly[3-(4-carboxybutyl)thiophene-2,5-diyl]-Na (P3CT-Na) film as the hole transport layer. The averaged power conversion efficiency (PCE) can be largely increased from 11.72 to 18.92% with a double-filtering process of the P3CT-Na solution mainly due to the increase in short-circuit current density (JSC) from 19.43 to 23.88 mA/cm2, which means that the molecular packing structure of P3CT-Na thin film can influence the formation of the MAPbI3 thin film and the contact quality at the MAPbI3/P3CT-Na interface. Zeta potentials, atomic-force microscopic images, absorbance spectra, photoluminescence spectra, X-ray diffraction patterns, and Raman scattering spectra are used to understand the improvement in the JSC. Besides, the light intensity-dependent and wavelength-dependent photovoltaic performance of the MAPbI3 solar cells shows that the P3CT-Na thin film is not only used as the hole transport layer but also plays an important role during the formation of a high-quality MAPbI3 thin film. It is noted that the PCE values of the best P3CT-Na based MAPbI3 solar cell are higher than 30% in the yellow-to-near infrared wavelength range under low light intensities. On the other hand, it is predicted that the double-filtering method can be readily used to increase the PCE of polymer based solar cells.


2022 ◽  
Author(s):  
Divya Sharma ◽  
Rajesh Mehra ◽  
Balwinder Raj

Abstract Mathematical modelling can offer the physical intuitions about the charge transport process inside a solar cells and provide the various elements affecting their performance. In the present paper, (CH3NH3Pb(I1-xBrx)3 based various perovskite solar cells have been mathematically simulated deploying SCAPS simulator. Various Hole Transport layers (HTLs) based on thickness, total defect density and donor density of mixed halide perovskite have been compared using Cd1-xZnxS as an Electron Transport Layer (ETL). Amongst the proffered HTLs, P3HT [Poly(3-hexylthiophene)] executed better and exhibited the PCE of 28.28%. During the simulation, mixed halide perovskite layer with thickness of 700 nm has been found suitable for the effective solar cell design. These mathematically simulated outcomes indicate the optimum efficiency of the solar cell that may further be prompted to design the extremely high efficient solar cells.


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