Tandem synthesis of tetrahydroquinolines and identification of reaction network by operando NMR

2021 ◽  
Author(s):  
Jingwen Chen ◽  
Long Qi ◽  
Biying Zhang ◽  
Minda Chen ◽  
Takeshi Kobayashi ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Complex Network ◽  
Reaction Network ◽  
Tandem Reactions ◽  
Organic P ◽  
Design And Optimization ◽  
Metal Organic ◽  
Tandem Synthesis

The study of the reaction mechanism and complex network for heterogeneously catalyzed tandem reactions is challenging but can guide reaction design and optimization. Here, we describe using a bifunctional metal-organic...

Tandem synthesis of ε‐caprolactam from cyclohexanone by an acidified metal‐organic framework

ChemCatChem ◽  
2021 ◽  
Author(s):  
Biying Zhang ◽  
Xinle Li ◽  
Jingwen Chen ◽  
Tianqing Liu ◽  
Andrew Cruz ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Tandem Synthesis ◽  
Organic Framework

Fabrication of High-Stable Metal-Organic Frameworks and Corresponding Hydrophobic Foam through a Reticular Chemistry Strategy for Simultaneous Organic Micropollutant and Insoluble Oil Removal from Wastewater

2021 ◽  
Author(s):  
Shuang Gai ◽  
Ruiqing Fan ◽  
Jian Zhang ◽  
Xuesong Zhou ◽  
Kai Xing ◽  
...  
Keyword(s):  
Smart Materials ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Oil Removal ◽  
Organic P ◽  
Metal Organic ◽  
Huge Challenge

Effective and simultaneous organic micropollutant and insoluble oil removal from wastewater by smart materials and feasible strategies is still a huge challenge. Herein, we design a novel two-dimensional (2D) metal-organic...

A nano-reactor based on PtNi@metal–organic framework composites loaded with polyoxometalates for hydrogenation–esterification tandem reactions

Nanoscale ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 3292-3299 ◽  
Author(s):  
Luning Chen ◽  
Xibo Zhang ◽  
Jinhong Zhou ◽  
Zhaoxiong Xie ◽  
Qin Kuang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Tandem Reactions ◽  
Metal Organic ◽  
Organic Framework

A nano-reactor based on PtNi@metal–organic framework composites loaded with polyoxometalates were successfully constructed and applied to hydrogenation–esterification tandem reactions.

Highly Stable Zr(IV)-Based Metal–Organic Frameworks with Chiral Phosphoric Acids for Catalytic Asymmetric Tandem Reactions

2019 ◽  
Vol 141 (18) ◽  
pp. 7498-7508 ◽  
Author(s):  
Wei Gong ◽  
Xu Chen ◽  
Hong Jiang ◽  
Dandan Chu ◽  
Yong Cui ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Tandem Reactions ◽  
Metal Organic ◽  
Catalytic Asymmetric ◽  
Phosphoric Acids

Metal-organic framework MIL-53(Al): synthesis, catalytic performance for the Friedel-Crafts acylation, and reaction mechanism

2015 ◽  
Vol 58 (10) ◽  
pp. 1544-1552 ◽  
Author(s):  
Junlei Yan ◽  
Sai Jiang ◽  
Shengfu Ji ◽  
Da Shi ◽  
Hefei Cheng
Keyword(s):  
Reaction Mechanism ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Metal Organic ◽  
Organic Framework

Thermodynamic complexity of carbon capture in alkylamine-functionalized metal–organic frameworks

2015 ◽  
Vol 3 (8) ◽  
pp. 4248-4254 ◽  
Author(s):  
D. Wu ◽  
T. M. McDonald ◽  
Z. Quan ◽  
S. V. Ushakov ◽  
P. Zhang ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Carbon Capture ◽  
Metal Organic Frameworks ◽  
Adsorption Calorimetry ◽  
Adsorption Enthalpy ◽  
Metal Organic

The CO2 adsorption enthalpy on an alkylamine-appended MOF, mmen-Mg2(dobpdc), was directly identified by adsorption calorimetry at 298, 323 and 348 K. The data suggest three adsorption events as function of coverage: two types of strong chemisorption and one weak physisorption. A multistage reaction mechanism was proposed.

Recent advances in post-synthetic modification of metal–organic frameworks: New types and tandem reactions

2019 ◽  
Vol 378 ◽  
pp. 500-512 ◽  
Author(s):  
Zheng Yin ◽  
Shuang Wan ◽  
Jian Yang ◽  
Mohamedally Kurmoo ◽  
Ming-Hua Zeng
Keyword(s):  
Metal Organic Frameworks ◽  
Tandem Reactions ◽  
Recent Advances ◽  
Metal Organic
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