scholarly journals Influence of pH-Neutral Lithium Polystyrenesulfonate Polyelectrolyte on the Energy Band Structure and Performance of Organic Solar Cells

2022 ◽  
Author(s):  
Merve Nur Ekmekci ◽  
Ju Hwan Kang ◽  
Yeasin Khan ◽  
Jung Hwa Seo ◽  
Bright Walker

Poly(3,4-ethylenedioxythiophene) : polystyrene sulfonate (PEDOT:PSS) is used ubiquitously in organic solar cells (OSCs) devices, however, it is not clear how the anionic PSS component by itself affects the band structure...

2019 ◽  
Vol 7 (15) ◽  
pp. 4449-4458
Author(s):  
Guangyou Pan ◽  
Jianhui Chen ◽  
Kunpeng Ge ◽  
Linlin Yang ◽  
Feng Li ◽  
...  

Novel ESCs is constructed by tunable energy band structure Zn(O,S) materials and incorporated in SHJ cells contributing to device performance.


2019 ◽  
Vol 21 (47) ◽  
pp. 26133-26145
Author(s):  
Ping Huang ◽  
Shunjian Xu ◽  
Meng Zhang ◽  
Wei Zhong ◽  
Zonghu Xiao ◽  
...  

The relation among microstructure of CQD, three characteristics of CQD (namely the spectra, energy band structure and functional groups) and photoelectric properties of QDSC has been built, providing guidance for the modulation doping of CQD.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Moyao Zhang ◽  
Qi Chen ◽  
Rongming Xue ◽  
Yu Zhan ◽  
Cheng Wang ◽  
...  

Abstract Charged defects at the surface of the organic–inorganic perovskite active layer are detrimental to solar cells due to exacerbated charge carrier recombination. Here we show that charged surface defects can be benign after passivation and further exploited for reconfiguration of interfacial energy band structure. Based on the electrostatic interaction between oppositely charged ions, Lewis-acid-featured fullerene skeleton after iodide ionization (PCBB-3N-3I) not only efficiently passivates positively charged surface defects but also assembles on top of the perovskite active layer with preferred orientation. Consequently, PCBB-3N-3I with a strong molecular electric dipole forms a dipole interlayer to reconfigure interfacial energy band structure, leading to enhanced built-in potential and charge collection. As a result, inverted structure planar heterojunction perovskite solar cells exhibit the promising power conversion efficiency of 21.1% and robust ambient stability. This work opens up a new window to boost perovskite solar cells via rational exploitation of charged defects beyond passivation.


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