scholarly journals Ultrafast photodissociation dynamics and nonadiabatic coupling between excited electronic states of methanol probed by time-resolved photoelectron spectroscopy

2019 ◽  
Vol 150 (11) ◽  
pp. 114301 ◽  
Author(s):  
Elio G. Champenois ◽  
Loren Greenman ◽  
Niranjan Shivaram ◽  
James P. Cryan ◽  
Kirk A. Larsen ◽  
...  
2020 ◽  
Author(s):  
Haiwang Yong ◽  
Andrés Moreno Carrascosa ◽  
Lingyu Ma ◽  
Brian Stankus ◽  
Michael P Minitti ◽  
...  

We present a comprehensive investigation of a recently introduced method to determine transient structures of molecules in excited electronic states with sub-Ångstrom resolution from time-resolved gas-phase scattering signals. The method,...


1988 ◽  
Vol 144 (1) ◽  
pp. 90-95 ◽  
Author(s):  
A.Yu. Chikishev ◽  
V.F. Kamalov ◽  
N.I. Koroteev ◽  
V.V. Kvach ◽  
A.P. Shkurinov ◽  
...  

2011 ◽  
Vol 10 (04) ◽  
pp. 509-518 ◽  
Author(s):  
HONG-BIN YAO ◽  
SHI-YING LIN ◽  
YU-JUN ZHENG

In this work, the nonadiabatic effects in the femtosecond photoionization of NaI molecule driven by pump and probe pulses are investigated theoretically using the accurate quantum wave packet method. The calculation with the inclusion of nonadiabatic coupling remarkably improves the agreement with experimental results of Jouvet et al. [J Phys Chen A101: 2555, 1997], indicating the importance of the nonadiabatic effect. Moreover, the dynamical evolutions of wave packets and their corresponding time-resolved photoelectron spectroscopy are presented both on the adiabatic and diabatic potentials. These comparisons contribute to further understanding of the influences of nonadiabatic effects in the femtosecond photoionization of NaI molecule.


2008 ◽  
Vol 10 (5) ◽  
pp. 053019 ◽  
Author(s):  
L Perfetti ◽  
P A Loukakos ◽  
M Lisowski ◽  
U Bovensiepen ◽  
M Wolf ◽  
...  

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