Syntheses of the two optical isomers of the insect anti-juvenile hormone agent ethyl p-[2-(t-Butylcarbonyloxy)butoxy]benzoate (ETB) and their biological activities

1983 ◽  
Vol 36 (7) ◽  
pp. 1409 ◽  
Author(s):  
DHS Horn ◽  
RH Nearn ◽  
JB Siddall ◽  
GB Staal ◽  
DC Cerf

The optical isomers (9) and (13) of the insect anti-juvenile hormone, (�)-ethyl p-[2-(t-butylcarbonyloxy)butoxy]benzoate (ETB) (14), have been synthesized and their biological activities examined in the tobacco hornworm Manduca sexta. It was found that the observed anti-juvenile hormone activity at low dose levels and juvenile hormone activity at higher levels in the Manduca sexta, after topical treatment with the racemic mixture (14) is due entirely to the (–)-enantiomer (9), the (+)-enantiomer (13) being completely inactive.

1989 ◽  
Vol 35 (3) ◽  
pp. 259-274 ◽  
Author(s):  
István Ujváry ◽  
György Matolcsy ◽  
Lynn M. Riddiford ◽  
Kiyoshi Hiruma ◽  
Kathleen L. Horwath

1965 ◽  
Vol 11 (12) ◽  
pp. 1641-1649 ◽  
Author(s):  
Howard A. Schneiderman ◽  
A. Krishnakumaran ◽  
V.G. Kulkarni ◽  
Lester Friedman

1972 ◽  
Vol 36 (5) ◽  
pp. 889-892 ◽  
Author(s):  
Masazumi NIHMURA ◽  
Soji AOMORI ◽  
Kenji MORI ◽  
Masanao MATSUI

1971 ◽  
Vol 61 (1) ◽  
pp. 41-48 ◽  
Author(s):  
W. R. Bransby-Williams

Cotton stainers (Dysdercus spp.) are members of the family Pyrrhocoridae and many are pests of cotton throughout the tropics. Ten species are found in Africa (Pearson, 1958). Three of these have been established in colonies at Arusha, Tanzania. They are D. cardinalis Gerst., D. fasciatus Sign. and D. nigrofasciatus Stål.


1968 ◽  
Vol 46 (9) ◽  
pp. 1467-1472 ◽  
Author(s):  
K. Subrahmania Ayyar ◽  
G. S. Krishna Rao

Synthetic work leading to the preparation of todomatuic acids (2a), juvabiones (2b), and ar-(±)-juvabione (8d) and the successful conversion of ar-(+)-turmerone (9) to ar-(+)-juvabione (3b) is presented. The synthetic compounds 2b and 3b exhibit juvenile hormone activity.


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