Preparation and Characterization of Core/Shell-like Intumescent Flame Retardant and its Application in Polypropylene

2009 ◽  
Vol 46 (8) ◽  
pp. 837-846 ◽  
Author(s):  
Kun Wu ◽  
Lei Song ◽  
Zhengzhou Wang ◽  
Yuan Hu ◽  
Everson Kandare ◽  
...  
RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20391-20402
Author(s):  
Chen Cheng ◽  
Yanling Lu ◽  
Weining Ma ◽  
Shaojie Li ◽  
Jun Yan ◽  
...  

Red phosphorus was coated by a polydopamine/melamine composite shell structure, which constituted an intumescent flame retardant with superior flame retardance and smoke suppression performance for epoxy resin.


2011 ◽  
Vol 399-401 ◽  
pp. 1376-1380
Author(s):  
Li Hua You ◽  
Yin Yin Hui ◽  
Xiang Ning Shi ◽  
Zhi Han Peng

In this study, a novel phosphorus-nitrogen containing intumescent flame retardant (P-N IFR) poly(melamine 2-carboxyethyl(phenyl) phosphate)(PMCEP) was prepared via the reaction of 2-carboxyethyl (phenyl) phosphinic acid (CEPPA) and melamine (MEL) in two-steps. Meanwhile, the molecular structure of the chemical compound was determined by FTIR,1H-NMR and elemental analysis; and the thermal properties was investigated by means of TGA. Combustion studies revealed high limiting oxygen index (LOI) indicative of better flame-retardancy properties for PBT resin.


Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 676
Author(s):  
Muting Wu ◽  
Wei Song ◽  
Yuzhang Wu ◽  
Wei Qu

A novel type of flame-retardant decorated plywood (FDP) was designed and prepared based on one kind of intumescent flame-retardant adhesive. The flame-retardant adhesive was composed of the phosphorous-nitrogen flame retardant and melamine urea formaldehyde (MUF) resin. An adhesive was placed between the plywood substrate and the decorative veneer. The shear strength of the FDP satisfied the Class II (GB/T 9846) when the ratio of flame-retardant and MUF was less than 0.65. The thermal stability of the flame-retardant adhesive was measured by thermogravimetric analysis (TGA). The intumescent behaviors of adhesives were systematically investigated. The morphological and chemical structures of the intumescent char of the flame-retardant adhesive were characterized by the scanning electron microscopy (SEM) and Fourier transform infrared spectra (FTIR), respectively. The fire performance of FDP was assessed by the cone calorimeter and the single burning item test. The FDP exhibited the most effective barrier when the optimized ratio of ammonium polyphosphate (APP) and pentaerythritol (PER) in the adhesive is 3. The flame-retardant class of FDP could be up to class B1(B) according to GB/T 8624.


RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 77545-77552 ◽  
Author(s):  
Lingfeng Xu ◽  
Caihong Lei ◽  
Ruijie Xu ◽  
Xiaoqing Zhang ◽  
Feng Zhang

α-ZrP was combined with polyphosphazene and formed a core–shell structure, which has a significant synergistic flame retardant performance in polypropylene.


2020 ◽  
Vol 44 (6) ◽  
pp. 814-824
Author(s):  
Yalin Xing ◽  
YanQiu Li ◽  
Zhaojun Lin ◽  
Xiao Ma ◽  
Hao Qu ◽  
...  

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