Amorphous silicon carbide photoelectrode for hydrogen production directly from water using sunlight

Author(s):  
F. Zhu ◽  
J. Hu ◽  
I. Matulionis ◽  
T. Deutsch ◽  
N. Gaillard ◽  
...  
Solar Energy ◽  
10.5772/8074 ◽  
2010 ◽  
Author(s):  
Feng Zhu ◽  
Jian Hu ◽  
Ilvydas Matulionis ◽  
Todd Deutsch ◽  
Nicolas Gaillard ◽  
...  

2009 ◽  
Vol 1171 ◽  
Author(s):  
Jian Hu ◽  
Feng Zhu ◽  
Ilvydas Matulionis ◽  
Todd Deutsch ◽  
Nicolas Gaillard ◽  
...  

AbstractWe report on an integrated photoelectrochemical (PEC) device for hydrogen production using amorphous silicon carbide (a-SiC:H) material as the photoelectrode in conjunction with an amorphous silicon (a-Si:H) tandem photovoltaic device. With the use of a-Si:H tandem solar cell, the flat-band potential of the hybrid PEC structure shifts significantly below the H2O/O2 half-reaction potential and is in an appropriate position to facilitate water splitting. Under reverse bias, saturated photocurrent of the hybrid device ranges between 3 to 5 mA/cm2 under AM1.5 light intensity. In a two-electrode setup (with ruthenium oxide counter electrode), which is analogous to a real PEC configuration, the hybrid cell produces photocurrent of about 0.83 mA/cm2at zero bias and hydrogen production is observed. The hybrid device exhibits good durability in pH2 buffered electrolyte for up to 150 hours (so far tested).


2008 ◽  
Vol 516 (12) ◽  
pp. 3855-3861 ◽  
Author(s):  
Kun Xue ◽  
Li-Sha Niu ◽  
Hui-Ji Shi ◽  
Jiwen Liu

Author(s):  
P. Musumeci ◽  
L. Calcagno ◽  
A. Makhtari ◽  
P. Baeri ◽  
G. Compagnini ◽  
...  

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