AbstractThe use of laboratory experiments as plasma creating sources is a valuable tool for understanding astrophysical observations. Recently plasma created through irradiation by lasers with relativistic intensities has been used to study effects of hot electrons and X-ray pumping on X-ray formation of multiply charged ions spectra. This paper discusses the formation of K-shell Fe spectra recorded from a plasma irradiated by 35 fs pulses with intensities of 1021 W/cm2. Modeling of the spectra suggests three different regions of plasma radiation including a cold ~10 eV region, a mild ~700 eV region, and a hot ~3500 eV region. The influence of hot electrons and X-ray pumping is discussed and a comparison with K-shell Fe spectra from a 1 MA X-pinch experiment is included to highlight the differences due to the shorter time frame of the laser–plasma interaction experiment.