scholarly journals Effective dielectric properties of Cement/Ba0.06(Na0.5Bi0.5)0.94TiO3 composites: A comparative approach

2021 ◽  
Vol 2070 (1) ◽  
pp. 012240
Author(s):  
Subrato ◽  
Amit Kumar ◽  
Manikant Paswan ◽  
K. Prasad

Abstract Lead-free ceramic powder of a morphotropic phase boundary composition Ba0.06(Na0.5Bi0.5)0.94TiO3 (BNBT) was prepared from a solid-state synthesis route. The cement-ceramic (1−ϕ)cement/ϕBNBT; 0 ≤ ϕ 1.0 composites were fabricated. The filler concentration-dependent values of the bulk density and real part of complex permittivity showed an increasing trend of variation while the apparent porosity and imaginary part of complex permittivity followed a decreasing trend. In order to test the acceptability of dielectric mixture equations of the inclusion material in the mixture, five such equations have been chosen. The Bruggeman, and Rother-Lichtenecker equations showed their coherence with minimal deviation from the experimental results of the real part of complex permittivity for the entire measurement range of volume fractions. Also, a first-order exponential growth/decay type of mathematical model was suggested which could fit the experimental data excellently well (r2 > 0.97).

Sensors ◽  
2019 ◽  
Vol 19 (9) ◽  
pp. 1968 ◽  
Author(s):  
Sylvie Bilent ◽  
Thi Hong Nhung Dinh ◽  
Emile Martincic ◽  
Pierre-Yves Joubert

This paper reports on the study of microporous polydimethylsiloxane (PDMS) foams as a highly deformable dielectric material used in the composition of flexible capacitive pressure sensors dedicated to wearable use. A fabrication process allowing the porosity of the foams to be adjusted was proposed and the fabricated foams were characterized. Then, elementary capacitive pressure sensors (15 × 15 mm2 square shaped electrodes) were elaborated with fabricated foams (5 mm or 10 mm thick) and were electromechanically characterized. Since the sensor responses under load are strongly non-linear, a behavioral non-linear model (first order exponential) was proposed, adjusted to the experimental data, and used to objectively estimate the sensor performances in terms of sensitivity and measurement range. The main conclusions of this study are that the porosity of the PDMS foams can be adjusted through the sugar:PDMS volume ratio and the size of sugar crystals used to fabricate the foams. Additionally, the porosity of the foams significantly modified the sensor performances. Indeed, compared to bulk PDMS sensors of the same size, the sensitivity of porous PDMS sensors could be multiplied by a factor up to 100 (the sensitivity is 0.14 %.kPa−1 for a bulk PDMS sensor and up to 13.7 %.kPa−1 for a porous PDMS sensor of the same dimensions), while the measurement range was reduced from a factor of 2 to 3 (from 594 kPa for a bulk PDMS sensor down to between 255 and 177 kPa for a PDMS foam sensor of the same dimensions, according to the porosity). This study opens the way to the design and fabrication of wearable flexible pressure sensors with adjustable performances through the control of the porosity of the fabricated PDMS foams.


2018 ◽  
Vol 2018 ◽  
pp. 1-7 ◽  
Author(s):  
M. P. F. Graça ◽  
K. D. A. Sabóia ◽  
F. Amaral ◽  
L. C. Costa

The CaCu3Ti4O12 (CCTO) ceramic powder was inserted in the polyvinyl alcohol (PVA) polymeric matrix, with an increasing weight fraction of the filler, to form a flexible and high dielectric constant composite at the GHz region. The structural characterization of the samples was performed using X-ray diffraction and scanning electron microscopy (SEM). The complex permittivity was calculated by the small perturbation theory using two resonant cavities (2.7 GHz and 5.0 GHz). Several classical models (Maxwell Garnett, Lichtenecker, effective medium theory (EMT), and Yamada) were used to fit the real part of the complex permittivity of the composite as a function of the weight fraction of CCTO powder inserted in the PVA matrix. The best predictions for the dielectric behavior of these samples were obtained with the EMT and Yamada models.


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