cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate
2012 ◽
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pp. m491-m491
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In the title compound, [PtCl2(C9H7N)2]·CH3NO2, the PtIIcation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl−anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl2N2unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent molecule is linked to the metal complex by weak intermolecular C—H...O hydrogen bonds.
2012 ◽
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