Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ2
O,O′)phenyl]pyrazol-1-yl-κN
2}acetato-κO)chloridozincate(II)]
2012 ◽
Vol 68
(6)
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pp. m817-m817
Keyword(s):
The asymmetric unit of the title compound, [Zn(C3H7NO)2(H2O)4][Zn(C13H10N2O5)Cl]2, is composed of a single anion and half a cation. The ZnII atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxylatomethoxy)phenyl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the ZnII atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry. In the crystal, the ions are linked by O—H...O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C—H...O and C—H...Cl interactions present, which lead to the formation of a three-dimensional structure.
2013 ◽
Vol 69
(12)
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pp. m672-m672
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2015 ◽
Vol 71
(2)
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pp. 136-138
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2015 ◽
Vol 71
(6)
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pp. 693-697
2012 ◽
Vol 68
(8)
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pp. m1114-m1114
2013 ◽
Vol 69
(12)
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pp. m640-m641
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2012 ◽
Vol 68
(6)
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pp. m761-m762
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2017 ◽
Vol 73
(3)
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pp. 403-406
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2014 ◽
Vol 70
(11)
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pp. 290-293
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2012 ◽
Vol 68
(8)
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pp. m1109-m1110