Crystal structure of chlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)manganese(III) 2-aminopyridine disolvate
2015 ◽
Vol 71
(2)
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pp. 165-167
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In the title compound, [Mn(C44H28N4)Cl]·2C5H6N2, the MnIIIcentre is coordinated by four pyrrole N atoms [averaged Mn—N = 2.012 (4) Å] of the tetraphenylporphyrin molecule and one chloride axial ligand [Mn—Cl = 2.4315 (7) Å] in a square-pyramidal geometry. The porphyrin macrocycle exhibits a non-planar conformation with majorrufflingandsaddlingdistortions. In the crystal, two independent solvent molecules form dimers through N—H...N hydrogen bonding. In these dimers, one amino N atom has a short Mn...N contact of 2.642 (1) Å thus completing the Mn environment in the form of a distorted octahedron, and another amino atom generates weak N—H...Cl hydrogen bonds, which link further all molecules into chains along theaaxis.
2018 ◽
Vol 74
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pp. 1751-1754
2016 ◽
Vol 72
(2)
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pp. 164-169
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2006 ◽
Vol 62
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pp. m728-m730
2016 ◽
Vol 72
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pp. 1077-1080
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2007 ◽
Vol 63
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pp. m2631-m2632
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2007 ◽
Vol 63
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pp. m2755-m2756
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2016 ◽
Vol 72
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pp. 907-911
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2014 ◽
Vol 70
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pp. o1085-o1086
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2006 ◽
Vol 62
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pp. o2043-o2044
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