Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
2020 ◽
Vol 76
(7)
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pp. 1136-1138
Keyword(s):
Exceptionally large crystals of posnjakite, Cu4SO4(OH)6(H2O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R 1 = 0.029 and revealed a structure based upon [Cu4(OH)6(H2O)O] sheets, which contain Jahn–Teller-distorted Cu octahedra. The sulfate tetrahedra are bonded to one side of the sheet via corner sharing and linked to successive sheets via extensive hydrogen bonds. The sulfate tetrahedra are split and rotated, which enables additional hydrogen bonds.
2018 ◽
Vol 74
(4)
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pp. 559-562
2012 ◽
Vol 68
(8)
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pp. o283-o287
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2018 ◽
Vol 74
(6)
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pp. 673-680
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2014 ◽
Vol 70
(11)
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pp. 424-426
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1997 ◽
Vol 68
(7)
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pp. 2909-2910
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2007 ◽
Vol 63
(11)
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pp. m2674-m2675
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