(3R,5S,7R,8R,9S,10S,12S,13R,14S)-10,13-Dimethyl-17-[5-oxo-5-(prop-2-yn-1-yloxy)pentan-2-yl]hexadecahydro-1H-cyclopenta[a]phenanthrene-3,7,12-triyl triacetate
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In the title compound, C33H48O8, four terminal H atoms of cholic acid are replaced by three acetyl and one terminal alkyne group. All the acetyl residues are twisted with respect to the rings (A, B and C) to which they are attached. The cyclopentane ring D adopts an envelope conformation with the methyl-substituted C atom as the flap. Rings A, B and C have chair conformations. The dihedral angle between the mean planes of rings C and D is 4.70 (11)°. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming a three-dimensional structure.
2014 ◽
Vol 70
(6)
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pp. o706-o706
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2014 ◽
Vol 70
(9)
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pp. o938-o939
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2017 ◽
Vol 73
(5)
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pp. 726-728
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2015 ◽
Vol 71
(1)
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pp. o33-o34
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2015 ◽
Vol 71
(1)
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pp. o58-o59
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2015 ◽
Vol 71
(1)
◽
pp. 35-37
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2015 ◽
Vol 71
(8)
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pp. o621-o622
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