Absorption Heat Pump/Refrigeration System Utilizing Ionic Liquid and Hydrofluorocarbon Refrigerants

2012 ◽  
Vol 134 (3) ◽  
Author(s):  
Sarah Kim ◽  
Yoon Jo Kim ◽  
Yogendra K. Joshi ◽  
Andrei G. Fedorov ◽  
Paul A. Kohl

The ionic liquid butylmethylimidazolium hexafluorophosphate (bmim)(PF6) and five different hydrofluorocarbon refrigerants were investigated as the working fluid pairs for a waste-heat driven absorption heat pump system for possible applications in electronics thermal management. A significant amount of the energy consumed in large electronic systems is used for cooling, resulting in low grade waste heat, which can be used to drive an absorption refrigeration system if a suitable working fluids can be identified. The Redlich–Kwong-type equation of state was used to model the thermodynamic conditions and the binary mixture properties at the corresponding states. The effects of desorber and absorber temperatures, waste-heat quality, and system design on the heat pump performance were investigated. Supporting experiments using R134a/(bmim)(PF6) as the working fluid pair were performed. Desorber and absorber outlet temperatures were varied by adjusting the desorber supply power and the coolant temperature at the evaporator inlet, respectively. For an evaporator temperature of 41 °C, which is relevant to electronics cooling applications, the maximum cooling-to-total-energy input was 0.35 with the evaporator cooling capability of 36 W and the desorber outlet temperature in the range of 50 to 110 °C.

Author(s):  
Yoon Jo Kim ◽  
Sarah Kim ◽  
Yogendra K. Joshi ◽  
Andrei G. Fedorov ◽  
Paul A. Kohl

An ionic-liquid (IL) is a salt in a liquid state usually with an organic cation and inorganic anion. ILs provide an alternative to the normally toxic working fluids in absorption systems, such as the ammonia/water system. They also eliminate the problems of poor temperature match, crystallization and metal-compatibility problems of the water/LiBr system. In the present study, an IL is explored the working fluid of a miniature absorption refrigeration system so as to utilize waste-heat within the system for low-cost, high-power electronics cooling. To determine performance benchmarks for the refrigerant/IL (e.g. [bmim][PF6]) pairs, system-level simulations have been carried out. An NRTL model was built and used to predict the solubility of the mixture as well as the mixture properties such as enthalpy and entropy. The properties of the refrigerants were determined using REFPROP 6.0. Saturation temperatures at the evaporator and condenser were 25°C and 50°C, respectively. Chip power was fixed at 100 W with the operating temperature set at 85°C. R32 gave the highest operating efficiency with the maximum coefficient of performance (COP) of ca. 0.55 while R134a and R152a showed comparable performance with the maximum COP of ca. 0.4 at the desorber outlet temperature of 80°C. When waste-heat is available for the system operation, R134a and R152a COPs were comparable or better than that of R32.


2021 ◽  
Vol 245 ◽  
pp. 01025
Author(s):  
Han Wang ◽  
Dali Yu ◽  
Chi Xu ◽  
Muhammad Salman Khan ◽  
Yunqing Bai

Small Modular Lead-based Reactor (SMLR) has generated great interest in academic research all around the world due to its good safety characteristics and relatively high core outlet temperature. In this paper, a Combined Cooling Heating and Power (CCHP) system with usage of absorption heat pump, which couples with a SMLR, was proposed to fulfill the energy demands in remote areas. Thermodynamic analysis was implemented to improve the performance of the CCHP system based on SMLR. To meet the remote areas’ energy needs, the main parameters and mass flow rate of a 35 MWth SMLR design were analyzed. The SMLR CCHP with absorption heat pump system can provide electric power 12.5MWe, heating 9.5MWh, and cooling 2.54MWc. The total energy utilization efficiency of the system can be 69.12 %. This work can provide a reference in the design and optimization of the CCHP system to meet the energy demands in the remote areas.


Author(s):  
Muhammad Kashif Shahzad ◽  
Yaqi Ding ◽  
Yongmei Xuan ◽  
Neng Gao ◽  
Guangming Chen

Open absorption heat pump (OAHP) system is more viable option to recover waste heat from moist gas as compared to the traditional condensation methods. This promising technology has great potential for latent heat recovery from moist gas, drying process in paper and other industrial heating applications. This study presents the process modelling and comparative analysis of OAHP system in Aspen Plus using two different solutions by adopting part regeneration technique. The promising potassium formate-water (HCOOK/H2O) which has lower causticity, lower costs and better crystallization characteristics is used as an alternative to the caustic lithium bromide-water (LiBr/H2O) solution in this study. Process model of the system is established in Aspen Plus and, the properties validity is confirmed with published experimental and Engineering Equation Solver (EES) library data. A detailed comparative parametric study is carried out to evaluate the effect of influencing parameters on coefficient of performance (COP), water recovery (φ) and heat recovery (ζ) efficiencies. The performance of OAHP system is found to be very similar using different concentrations as 2.13 COP value for 50% LiBr/H2O and 2.19 for 70% HCOOK/H2O solution over design conditions. Similarly, φ is found to be 0.701, 0.688 while ζ as 0.716 and 0.705 for both the absorbents. Moreover, the system’s operational concentration range is 45-61.3% for LiBr/H2O and 55-82.1% for HCOOK/H2O at 135 °C regeneration heat input. Potassium formate solution having quite similar properties to the aqueous lithium bromide is also confirmed to have similar performance trends using 50% and 70% concentrations.


2010 ◽  
Vol 121-122 ◽  
pp. 986-991
Author(s):  
Jing Gang Wang ◽  
Xiao Xia Gao ◽  
Bo Liang ◽  
Hua Hui Zhou

A large number of cooling water exists in chemical plant, use water source heat pump and lithium bromide absorption heat pump system to achieve water cooling instead of cooling tower, at the same time, extract heat for building cooling and heating. Respectively introduced the summer cooling system and winter heating system, and a feasibility analysis was carried out. The conclusion is get: water source heat pump system and lithium bromide absorption heat pump system for cooling water waste heat recovery is certain feasibility; the environment optimization can be achieved in chemical plant, at the same time, energy conservation and emission reduction is realized.


2020 ◽  
Vol 220 ◽  
pp. 113072 ◽  
Author(s):  
Z.Y. Xu ◽  
J.T. Gao ◽  
H.C. Mao ◽  
D.S. Liu ◽  
R.Z. Wang

2013 ◽  
Vol 291-294 ◽  
pp. 1670-1674
Author(s):  
Biao Li ◽  
Jiang Fan

It is the new way of the thermal power plant energy conservation to recycling plant circulating water waste heat for heating with the heat pump technology. The recovery of low temperature waste heat is the background. And lithium bromide absorption heat pump is the object of this study. The impact of changes in temperature parameters on the performance of heat pump unit is analyzed. As a theoretical basis for the design of the heat pump system and power plant heat pump unit’s optimal operation provide a reference. The result provides a theoretical reference for the optimal operation of the heat pump system design and power plant heat pump units.


2017 ◽  
Vol 25 (04) ◽  
pp. 1730005 ◽  
Author(s):  
Dae Hoon Kang ◽  
Sun-Ik Na ◽  
Min Soo Kim

This paper reviews the latest researches on steam generation heat pump (SGHP) to cover diverse technologies to enhance the performance depending on its applications. High temperature heat pump that can produce steam was reviewed first, and SGHP which recovers waste heat from low grade heat source (evaporator) was outlined. Conventional waste heat recovery from many industrial sites was reviewed, and SGHP to produce higher temperature steam by re-compression after heat sink (condenser) was discussed.


Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1022
Author(s):  
Xinxin Zhang ◽  
Yin Zhang ◽  
Zhenlei Li ◽  
Jingfu Wang ◽  
Yuting Wu ◽  
...  

The organic Rankine cycle (ORC) is a popular and promising technology that has been widely studied and adopted in renewable and sustainable energy utilization and low-grade waste heat recovery. The use of zeotropic mixtures in ORC has been attracting more and more attention because of the possibility to match the temperature profile of the heat source by non-isothermal phase change, which reduces the irreversibility in the evaporator and the condenser. The selection of working fluid and expander is strongly interconnected. As a novel expander, a single screw expander was selected and used in this paper for efficient utilization of the wet zeotropic mixtures listed in REFPROP 9.1 in a low-temperature subcritical ORC system. Five indicators, namely net work, thermal efficiency, heat exchange load of condenser, temperature glide in evaporator, and temperature glide in condenser, were used to analyze the performance of an ORC system with wet and isentropic zeotropic mixtures as working fluids. The calculation and analysis results indicate that R441A with an expander outlet temperature of 320 K may be the suitable zeotropic mixture used for both open and close type heat source. R436B may be selected with an expander outlet temperature of 315 K. R432A may be selected with an expander outlet temperature from 295 K to 310 K.


Author(s):  
Marko Ilic ◽  
Velimir Stefanović ◽  
Saša Pavlović ◽  
Gradimir Ilić

The paper presents an initial CFD study on adopting the biomass-pellet usage in a generator of an absorption heat pump by obtaining the temperature field inside the biomass furnace. Contemporary absorption technologies are mostly based on the use of gas and other waste heat as a driving force in the Generator, where the two-component working fluid splits into the refrigerant and the absorbent. There are few or no absorption heat pumps that work directly on biomass - pellets. In the Balkans, biomass - pellets are a frequent and renewable source of thermal energy. The aim of this paper is to initially research the possibility of an absorption generator to work directly on available pellets. Following this idea, a comprehensive overview of contemporary absorption technology is given with a physical and mathematical model of the small pellet stove in FLUENT, which will be modified to adapt the generator. In the beginning, temperature fields are obtained by simulation inside the furnace and on its surfaces. Work showed that the temperature field has enough potential for triggering the absorption process as temperatures in the upper part of the stove are above 400°C at the heating capacity of around 13 kW up to 20 kW. The implemented work and the obtained results could serve as a useful reference for further design and optimization of the generator of AHP for direct Biomass utilization for a middle size system.


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