Development of a Natural Gas-Fired, Ultra-Low NOx Can Combustor for an 800 KW Gas Turbine

Author(s):  
K. O. Smith ◽  
A. C. Holsapple ◽  
H. K. Mak ◽  
L. Watkins

The experimental results from the rig testing of an ultra-low NOx, natural gas-fired combustor for an 800 to 1000 kw gas turbine are presented. The combustor employed lean-premixed combustion to reduce NOx emissions and variable geometry to extend the range over which low emissions were obtained. Testing was conducted using natural gas and methanol. Testing at combustor pressures up to 6 atmospheres showed that ultra-low NOx emissions could be achieved from full load down to approximately 70% load through the combination of lean-premixed combustion and variable primary zone airflow.

Author(s):  
K. O. Smith ◽  
M. H. Samii ◽  
H. K. Mak

The results of an on-engine evaluation of an ultra-low NOx, natural gas-fired combustor for a 200 kW gas turbine are presented. The combustor evaluated used lean-premixed combustion to reduce NOx emissions and variable geometry to extend the range over which low emissions were obtained. Test results showed that ultra-low NOx emissions could be achieved from full load down to approximately 50% load through the combination of lean-premixed combustion and variable primary zone airflow.


Author(s):  
Iarno Brunetti ◽  
Giovanni Riccio ◽  
Nicola Rossi ◽  
Alessandro Cappelletti ◽  
Lucia Bonelli ◽  
...  

The use of hydrogen as derived fuel for low emission gas turbine is a crucial issue of clean coal technology power plant based on IGCC (Integrated Gasification Combined Cycle) technology. Control of NOx emissions in gas turbines supplied by natural gas is effectively achieved by lean premixed combustion technology; conversely, its application to NOx emission reduction in high hydrogen content fuels is not a reliable practice yet. Since the hydrogen premixed flame is featured by considerably higher flame speed than natural gas, very high air velocity values are required to prevent flash-back phenomena, with obvious negative repercussions on combustor pressure drop. In this context, the characterization of hydrogen lean premixed combustion via experimental and modeling analysis has a special interest for the development of hydrogen low NOx combustors. This paper describes the experimental and numerical investigations carried-out on a lean premixed burner prototype supplied by methane-hydrogen mixture with an hydrogen content up to 100%. The experimental activities were performed with the aim to collect practical data about the effect of the hydrogen content in the fuel on combustion parameters as: air velocity flash-back limit, heat release distribution, NOx emissions. This preliminary data set represents the starting point for a more ambitious project which foresees the upgrading of the hydrogen gas turbine combustor installed by ENEL in Fusina (Italy). The same data will be used also for building a computational fluid dynamic (CFD) model usable for assisting the design of the upgraded combustor. Starting from an existing heavy-duty gas turbine burner, a burner prototype was designed by means of CFD modeling and hot-wire measurements. The geometry of the new premixer was defined in order to control turbulent phenomena that could promote the flame moving-back into the duct, to increase the premixer outlet velocity and to produce a stable central recirculation zone in front of the burner. The burner prototype was then investigated during a test campaign performed at the ENEL’s TAO test facility in Livorno (Italy) which allows combustion test at atmospheric pressure with application of optical diagnostic techniques. In-flame temperature profiles, pollutant emissions and OH* chemiluminescence were measured over a wide range of the main operating parameters for three fuels with different hydrogen content (0, 75% and 100% by vol.). Flame control on burner prototype fired by pure hydrogen was achieved by managing both the premixing degree and the air discharge velocity, affecting the NOx emissions and combustor pressure losses respectively. A CFD model of the above-mentioned combustion test rig was developed with the aim to validate the model prediction capabilities and to help the experimental data analysis. Detailed simulations, performed by a CFD 3-D RANS commercial code, were focused on air/fuel mixing process, temperature field, flame position and NOx emission estimation.


Author(s):  
P. Gokulakrishnan ◽  
C. C. Fuller ◽  
R. G. Joklik ◽  
M. S. Klassen

Single digit NOx emission targets as part of gas turbine design criteria require highly accurate modeling of the various NOx formation pathways. The concept of lean, premixed combustion is adopted in various gas turbine combustor designs, which achieves lower NOx levels by primarily lowering the flame temperature. At these conditions, the post-flame thermal-NOx pathway contribution to the total NOx can be relatively small compared to that from the prompt-NOx and the N2O-route, which are enhanced by the super-equilibrium radical pathway at the flame front. In addition, new sources of natural gas fuel (e.g., imported LNG) with widely varying chemical compositions including higher order hydrocarbon components, impact flame stability, lean blow-out limits and emissions in existing lean premixed combustion systems. Also, the presence of higher order hydrocarbons can increase the risk of flashback induced by autoignition in the premixing section of the combustor. In this work a detailed chemical kinetic model was developed for natural gas fuels that consist of CH4, C2H6, C3H8, nC4H10, iC4H10, and small amounts of nC5H12, iC5H12 and nC6H14 in order to predict ignition behavior at typical gas turbine premixing conditions and to predict CO and NOx emissions at lean premixed combustion conditions. The model was validated for different NOx-pathways using low and high pressure laminar premixed flame data. The model was also extended to include a vitiated kinetic scheme to account for the influence of exhaust gas recirculation on fuel oxidation. The model was employed in a chemical reactor network to simulate a laboratory scale lean premixed combustion system to predict CO and NOx. The current kinetic mechanism demonstrates good predictive capability for NOx emissions at lower temperatures typical of practical lean premixed combustion systems.


Author(s):  
Jeffrey Armstrong ◽  
Douglas Hamrin ◽  
Steve Lampe

Dry, low NOx emissions developments in the industrial gas turbine industry have focused on lean-premixed combustion to reduce NOx to single digit parts-per-million (ppmV) emissions. The reduction of thermal NOx is limited by the lowest lean-premix combustion temperatures. To overcome this limit, a thermal oxidizer is applied which can oxidize hydrocarbon fuels at temperatures below those of lean-premixed combustion in a Brayton cycle. This oxidation technique is explained in a combustion taxonomy model. This paper presents the historical development and demonstration of technology with two different recuperated gas turbines operating on landfill gas. A unique fuel-injection strategy was used to introduce the fuel into the inlet of the gas turbine’s air compressor. The technology demonstrated an order-of-magnitude reduction in the emissions of NOx to the parts-per-billion range.


Author(s):  
Shigeru Hayashi ◽  
Hideshi Yamada ◽  
Kazuo Shimodaira

The development of a variable geometry lean-premixed combustor is in progress at NAL. Engine testing has been cooducted by using a natural gas-fueled 210-kW gas turbine to demonstrate the capability of ultra-low NOx emissions over a wide range of eogine operation. This paper describes the effort of engine testing of the combustor to achieve NOx emissions of the 10-ppm level. Fuel was staged to the non-premixed pilot and premixed main burners. A butterfly valve air splitting system was employed to maintain both low NOx emissions and high efficieocy over a wide operating range of the engine. The engioe was operated in the lean-premixed, low NOx emissions mode from idle to full power. Over the whole operating conditions from idle to full power, NOx emissions were reduced to levels less than 25 ppm (15% O2 dry). The NOx emissions level for a nearly constant combustion efficiency decreased with increasing power or turbine inlet temperature. At operating conditions of 90% to full power, NOx emissions levels of 12 to 8 ppm (15% O2 dry) were measured with combustion efficiencies of 99.7 to 99.1%.


Author(s):  
Don Ferguson ◽  
Geo. A. Richard ◽  
Doug Straub

In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for today’s engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.


Author(s):  
Candy Hernandez ◽  
Vincent McDonell

Abstract Lean-premixed (LPM) gas turbines have been developed for stationary power generation in efforts to reduce emissions due to strict air quality standards. Lean-premixed operation is beneficial as it reduces combustor temperatures, thus decreasing NOx formation and unburned hydrocarbons. However, tradeoffs occur between system performance and turbine emissions. Efforts to minimize tradeoffs between stability and emissions include the addition of hydrogen to natural gas, a common fuel used in stationary gas turbines. The addition of hydrogen is promising for both increasing combustor stability and further reducing emissions because of its wide flammability limits allowing for lower temperature operation, and lack of carbon molecules. Other efforts to increase gas turbine stability include the usage of a non-lean pilot flame to assist in stabilizing the main flame. By varying fuel composition for both the main and piloted flows of a gas turbine combustor, the effect of hydrogen addition on performance and emissions can be systematically evaluated. In the present work, computational fluid dynamics (CFD) and chemical reactor networks (CRN) are created to evaluate stability (LBO) and emissions of a gas turbine combustor by utilizing fuel and flow rate conditions from former hydrogen and natural gas experimental results. With CFD and CRN analysis, the optimization of parameters between fuel composition and main/pilot flow splits can provide feedback for minimizing pollutants while increasing stability limits. The results from both the gas turbine model and former experimental results can guide future gas turbine operation and design.


Author(s):  
David G. Nicol ◽  
Robert C. Steele ◽  
Nick M. Marinov ◽  
Philip C. Malte

This study addresses the importance of the different chemical pathways responsible for NOx formation in lean-premixed combustion, and especially the role of the nitrous oxide pathway relative to the traditional Zeldovich pathway. NOx formation is modeled and computed over a range of operating conditions for the lean-premixed primary zone of gas turbine engine combustors. The primary zone, of uniform fuel-air ratio, is modeled as a micro-mixed well-stirred reactor, representing the flame zone, followed by a series of plug flow reactors, representing the post-flame zone. The fuel is methane. The fuel-air equivalence ratio is varied from 0.5 to 0.7. The chemical reactor model permits study of the three pathways by which NOx forms, which are the Zeldovich, nitrous oxide, and prompt pathways. Modeling is also performed for the well-stirred reactor alone. Three recently published, complete chemical kinetic mechanisms for the C1-C2 hydrocarbon oxidation and the NOx formation are applied and compared. Verification of the model is based on the comparison of its NOx output to experimental results published for atmospheric pressure jet-stirred reactors and for a ten atmosphere porous-plate burner. Good agreement between the modeled results and the measurements is obtained for most of the jet-stirred reactor operating range. For the porous-plate burner, the model shows agreement to the NOx measurements within a factor of two, with close agreement occurring at the leanest and coolest cases examined. For lean-premixed combustion at gas turbine engine conditions, the nitrous oxide pathway is found to be important, though the Zeldovich pathway cannot be neglected. The prompt pathway, however, contributes small-to-negligible NOx. Whenever the NOx emission is in the 15 to 30ppmv (15% O2, dry) range, the nitrous oxide pathway is predicted to contribute 40 to 45% of the NOx for high pressure engines (30atm), and 20 to 35% of the NOx for intermediate pressure engines (10atm). For conditions producing NOx of less than 10ppmv (15% O2, dry), the nitrous oxide contribution increases steeply and approaches 100%. For lean-premixed combustion in the atmospheric pressure jet-stirred reactors, different behavior is found. All three pathways contribute; none can be dismissed. No universal behavior is found for the pressure dependence of the NOx. It does appear, however, that lean-premixed combustors operated in the vicinity of 10atm have a relatively weak pressure dependence, whereas combustors operated in the vicinity of 30atm have an approximately square root pressure dependence of the NOx.


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