A New Probabilistic Model for High-pH Stress Corrosion Cracking

Author(s):  
Andrew Francis ◽  
Chas Jandu

Stress corrosion cracking (SCC) poses a threat to integrity of buried pipelines in many parts of the world. In North America there is now a requirement that integrity management plans should address SCC and a direct assessment methodology, SCCDA, for managing the threat due to SCC, is now becoming established. Like general corrosion or fatigue, SCC is a time dependent deterioration process that leads to progressive weakness of the pipe wall eventually causing failure as a leak or rupture, if not managed. There are indeed two known forms of SCC; High-pH and near neutral-pH SCC. The focus of this paper is on High-pH SCC. High-pH SCC involves a number of phases including incubation, initiation, anodic growth, coalescence, mechanical growth and final failure. Factors affecting these processes include temperature, static and cyclic stress, soil conditions, type of coating and level of Cathodic Protection. Some of these factors may vary seasonally. The temporal development of SCC damage is thus both complex and subject to significant uncertainty. The purpose of this paper is to describe a detailed probabilistic model that addresses the various phases of High-pH SCC taking account of uncertainty in the relevant influencing factors. The model determines the likely times to coalescence and to grow to a critical size thus providing a time dependent probability of failure. The model gives a clear indication of which parameters should be managed in order to reduce the likelihood of failure to an acceptable level. The model provides the basis of a powerful decision making tool for the purpose of managing High pH SCC. Consequently, the model can be used in conjunction with relevant in-line inspection data and/or above ground survey data to provide an effective SCC integrity management tool. The model is illustrated through a numerical example and the use of the model as an integrity management tool is clearly demonstrated.

Author(s):  
Hamid Niazi ◽  
Shidong Wang ◽  
Lyndon Lamborn ◽  
Reg Eadie ◽  
Weixing Chen ◽  
...  

Author(s):  
Zhigang Wei ◽  
Limin Luo ◽  
Marek Rybarz ◽  
Kamran Nikbin

Corrosion-fatigue and stress corrosion cracking have long been recognized as the principal degradation and failure mechanisms of materials under combined corrosive environment and sustained/cyclic loading conditions. These phenomena are strongly material and environment dependent, and cycle-dependent fatigue and time-dependent matter diffusion/chemical reaction at the crack tip can be operational simultaneously. How to include these cycle-dependent and time-dependent phenomena in a single model and how to study the failure mechanisms interaction are big challenges posed to material scientists and engineers. In this paper the current linear superposition theories for modeling cycle-dependent and time-dependent corrosion-fatigue and stress corrosion cracking phenomena are reviewed first. Subsequently, a generalized nonlinear superposition theory is proposed to incorporate possible nonlinear interaction or synergistic effect among the underlying mechanisms. The unified model derived from the new theory, depending on the specific materials and loading condition and environment, can be reduced to pure corrosion, pure fatigue, stress corrosion cracking and corrosion-fatigue. Finally, for the first time, a new breakthrough parameter is defined in this paper to quantitatively describe the interaction or synergistic effect between two different operating mechanisms, such as time- and cycle-dependent mechanisms.


Author(s):  
John E. Broussard ◽  
Shannon Chu ◽  
Kevin Fuhr

A probabilistic model was developed that considers the likelihood of through-wall penetration of chloride-induced stress corrosion cracking (CISCC) in austenitic stainless steel canisters and compares different population-based sample inspection regimes. This paper describes the inputs and methods used to simulate multiple canisters with a range of susceptibilities. This paper also summarizes results of key illustrative cases.


2005 ◽  
Vol 297-300 ◽  
pp. 939-944 ◽  
Author(s):  
Wu Yang ◽  
Guang Fu Li ◽  
Hao Guo ◽  
Jian Jiang Zhou ◽  
Chun Bo Huang ◽  
...  

Effects of some environmental factors on stress corrosion cracking (SCC) of pipeline steel X-70 both in near-neutral pH environments, including NS4 solution and several solutions containing main types of soil in the eastern part of China, and in high pH solution were studied by means of electrochemical measurement and slow strain rate testing (SSRT). The anodic polarization curves showed different features in near-neutral pH and high pH solutions in terms of active-passive transition behavior. In near-neutral pH solutions, the cracking mode was transgranular with the feature of quasi-cleavage, the susceptibility to SCC increased with decreasing potential, pH and temperature as well as increasing CO2, indicating a dominant mechanism of hydrogen induced cracking (HIC). In high pH solutions, the cracking behavior was similar to that in near-neutral pH solutions when the specimens were polarized at cathodic potentials, but quite different at anodic potentials. A comparison of the electrochemical behavior with the SCC potential region indicated a dominant SCC mechanism associated with anodic dissolution (AD) of X70 in high pH solution at anodic potentials. A preliminary experimental potential (E)-pH-SCC diagram has been established for X70 in near-neutral pH environments.


CORROSION ◽  
1966 ◽  
Vol 22 (6) ◽  
pp. 178-179 ◽  
Author(s):  
H. E. JOHNSON ◽  
J. LEJA

Abstract Stress corrosion cracking of alpha brass in ammonia solutions containing copper-ammonia complexes is most rapid in the pH range 6 to 7, where weight loss corrosion is insignificant, Linear relationships were found for (a) log 1/tc (tc = cracking time) vS log Cu++ (initial copper concentration) and (b) l/tc vs 1/T (T = absolute temperature). Oxygen appears necessary for general corrosion and cracking at pH values above 8. Rapid cracking is interpreted in terms of a drastic surface free energy decrease caused by the adsorption of an intermediate copper-zinc- ammonia complex (not yet identified) which is catalytically formed at the brass/solution interface and is surface active. It is suggested also that linear relationships like (a) and (b) above may be distinguishing features of stress corrosion cracking mechanisms which involve surface energy lowering.


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