scholarly journals Growth and defect crystal structure of CdF2 and nonstoichiometric Cd1−x R x F2+x phases (R = rare earth elements and In). Part 3. Crystal structure of As-grown Cd0.90 R 0.10F2.10(R = Sm-Lu, Y) single crystals

2005 ◽  
Vol 50 (5) ◽  
pp. 892-892
Author(s):  
E. A. Sul’yanova ◽  
A. P. Shcherbakov ◽  
V. N. Molchanov ◽  
V. I. Simonov ◽  
B. P. Sobolev
1988 ◽  
Vol 133 ◽  
Author(s):  
C. T. Liu ◽  
J. A. Horton ◽  
D. G. Petitifor

ABSTRACTRare-earth elements including Y, Er and Sc were added to AlTi3 for stabilizing the Ll2 ordered crystal structure, as predicted by the AB3 structure map. The crystal structure and phase composition in the AlTi3 alloys were studied by electron microprobe analysis, X-ray diffraction and TEM. The solubility limit of the rare-earth elements were determined and correlated with the atomic size factor. The results obtained so far indicate that rare-earth additions are unable to change the crystal structure of AlTi3 from DO19 to Ll2. The inability to stabilize the Ll2 structure demonstrates the need to characterize the structure map domains with a further period-dependent parameter.


Nanoscale ◽  
2021 ◽  
Author(s):  
Rui Shi ◽  
Carlos D S Brites ◽  
Luis Antonio Dias Carlos

The hexagonal-phase (β) of NaREF4 upconversion nanocrystals (RE = rare earth elements) has been widely employed because of the outstanding luminescence performance, yet less is known about the essence of...


1995 ◽  
Vol 50 (4) ◽  
pp. 577-580 ◽  
Author(s):  
H. Szillat ◽  
Hk. Müller-Buschbaum

Single crystals of (Cu0.22Mg0.78)BaNd2Mo4O16 have been prepared by crystallization from melts and investigated by X-ray methods. The compound crystallizes monoclinically, space group C62h - C12/c1, Z = 4, a = 5.351(1), b = 12.891(2), c = 19.391(4) Å,β = 90.899(14)° and is isotypic to CuKHo2Mo4O16. The crystal structure is dominated by BaO10 and NdO8 polyhedra forming a three-dimensional polyhedra network, which is filled by axially distorted (Cu,Mg)O6 octahedra and MoO4 tetrahedra.


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