Synthesis and Characterization of Ru(II) Polypyridyl Complexes with 2-(4-Methylbenzoate)-1H-imidazo[4,5-f][1,10]phenantroline Ligand, and Their DNA Binding, Photocleavage, Physico-Chemical Properties, and Cytotoxicity

2020 ◽  
Vol 90 (12) ◽  
pp. 2456-2466
Author(s):  
C. Nagamani ◽  
P. V. Reddy ◽  
M. R. Reddy ◽  
K. L. Reddy ◽  
S. Satyanarayana
RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61566-61575 ◽  
Author(s):  
A. Vasanthakumar ◽  
I. Bahadur ◽  
G. Redhi ◽  
R. M. Gengan

Important physico-chemical properties of ionic liquids (ILs) can be manipulated by adjusting the nature of the cation or anion.


2016 ◽  
Vol 53 (3) ◽  
pp. 249-258 ◽  
Author(s):  
Manickam Janarthana Umapathy ◽  
Venu Lakshimi Narayanan ◽  
P. Magesan ◽  
P. Chiranjeevi ◽  
Susan W. Jemima

1981 ◽  
Vol 1 (3-4) ◽  
pp. 201-224 ◽  
Author(s):  
Eric G. Derouane ◽  
Serge Determmerie ◽  
Zelimir Gabelica ◽  
Niels Blom

2014 ◽  
Vol 617 ◽  
pp. 174-178 ◽  
Author(s):  
Chrystelle Neaime ◽  
Nicolas Nerambourg ◽  
Tangi Aubert ◽  
Fabien Grasset ◽  
Stephane Cordier ◽  
...  

The design, synthesis and characterization of magnetic-luminescent nanoparticles is now more and more studied since the last decade. However, optimizing the design of such materials requires a deep understanding of their physico-chemical properties. In this paper are reported extended investigations on luminescent and magnetic @SiO2 Nps prepared by a water-in-oil microemulsion technique. The Cs2[Mo6Br14] cluster compound is used as red-NIR phosphor and is prepared by solid state chemistry. We bring here new insights into the structure of such Nps and its interplay with their optical or magnetic properties.


2018 ◽  
Vol 74 (1-2) ◽  
pp. 35-43
Author(s):  
Wei Gao ◽  
Muhammad Kamran Siddiqui ◽  
Najma Abdul Rehman ◽  
Mehwish Hussain Muhammad

Abstract Dendrimers are large and complex molecules with very well defined chemical structures. More importantly, dendrimers are highly branched organic macromolecules with successive layers or generations of branch units surrounding a central core. Topological indices are numbers associated with molecular graphs for the purpose of allowing quantitative structure-activity relationships. These topological indices correlate certain physico-chemical properties such as the boiling point, stability, strain energy, and others, of chemical compounds. In this article, we determine hyper-Zagreb index, first multiple Zagreb index, second multiple Zagreb index, and Zagreb polynomials for hetrofunctional dendrimers, triangular benzenoids, and nanocones.


2014 ◽  
Vol 70 (a1) ◽  
pp. C1223-C1223
Author(s):  
Jason Benedict ◽  
Ian Walton ◽  
Dan Patel ◽  
Jordan Cox

Metal-organic Frameworks (MOFs) remain an extremely active area of research given the wide variety of potential applications and the enormous diversity of structures that can be created from their constituent building blocks. While MOFs are typically employed as passive materials, next-generation materials will exhibit structural and/or electronic changes in response to applied external stimuli including light, charge, and pH. Herein we present recent results in which advanced photochromic diarylethenes are combined with MOFs through covalent and non-covalent methods to create photo-responsive permanently porous crystalline materials. This presentation will describe the design, synthesis, and characterization of next-generation photo-switchable diarylethene based ligands which are subsequently used to photo-responsive MOFs. These UBMOF crystals are, by design, isostructural with previously reported non-photoresponsive frameworks which enables a systematic comparison of their physical and chemical properties. While the photoswitching of the isolated ligand in solution is fully reversible, the cycloreversion reaction is suppressed in the UBMOF single crystalline phase. Spectroscopic evidence for thermally induced cycloreversion will be presented, as well as a detailed analysis addressing the limits of X-ray diffraction techniques applied to these systems.


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